Wiley
Helvetica Chimica Acta
,  том 54 ,  издание 8 ,  страницы 2889-2895

Eine neuartige Fragmentierung bicyclischer Enoläther Verfahren zur Darstellung macrocyclischer Lactone

Тип публикации: Journal Article
Дата публикации: 1971-12-10
Wiley
scimago Q2
wos Q3
БС2
SJR: 0.491
CiteScore: 3
Impact factor: 1.8
ISSN: 0018019X, 15222675
Catalysis
Organic Chemistry
Drug Discovery
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Vicinal α-hydroperoxy-tetrahydropyranyl ethers annelated to cyclododecane are smoothly converted by homolytic fission in about 75% yield to a mixture of the macrocyclic lactones 3, 4, and 5. Based on this observation, an economically feasible synthesis of Exaltolide1 (>65% yield) has been developed. The mechanism of this new β-fragmentation reaction is discussed.
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Becker J., Ohloff G. Eine neuartige Fragmentierung bicyclischer Enoläther Verfahren zur Darstellung macrocyclischer Lactone // Helvetica Chimica Acta. 1971. Vol. 54. No. 8. pp. 2889-2895.
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Becker J., Ohloff G. Eine neuartige Fragmentierung bicyclischer Enoläther Verfahren zur Darstellung macrocyclischer Lactone // Helvetica Chimica Acta. 1971. Vol. 54. No. 8. pp. 2889-2895.
RIS |
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RIS Скопировать
TY - JOUR
DO - 10.1002/hlca.19710540854
UR - https://doi.org/10.1002/hlca.19710540854
TI - Eine neuartige Fragmentierung bicyclischer Enoläther Verfahren zur Darstellung macrocyclischer Lactone
T2 - Helvetica Chimica Acta
AU - Becker, J.
AU - Ohloff, G.
PY - 1971
DA - 1971/12/10
PB - Wiley
SP - 2889-2895
IS - 8
VL - 54
SN - 0018-019X
SN - 1522-2675
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{1971_Becker,
author = {J. Becker and G. Ohloff},
title = {Eine neuartige Fragmentierung bicyclischer Enoläther Verfahren zur Darstellung macrocyclischer Lactone},
journal = {Helvetica Chimica Acta},
year = {1971},
volume = {54},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/hlca.19710540854},
number = {8},
pages = {2889--2895},
doi = {10.1002/hlca.19710540854}
}
MLA
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Becker, J., and G. Ohloff. “Eine neuartige Fragmentierung bicyclischer Enoläther Verfahren zur Darstellung macrocyclischer Lactone.” Helvetica Chimica Acta, vol. 54, no. 8, Dec. 1971, pp. 2889-2895. https://doi.org/10.1002/hlca.19710540854.