volume 654, issue 1, pages 146-160
Ringöffnungen der Azole, VII. Zur Thermolyse des 5‐Phenyl‐tetrazols
Publication type: Journal Article
Publication date: 1962-06-15
—
Organic Chemistry
Physical and Theoretical Chemistry
General Medicine
Abstract
Die Thermolyse von 5-Phenyl-tetrazol in Mesitylen und anderen Solventien liefert 3.6-Diphenyl-dihydro-1.2.4.5-tetrazin (VI), 4-Amino-3.5-diphenyl-1.2.4-triazol (IX), 3.5-Diphenyl-1.2.4-triazol (V), 2.4.6-Triphenyl-1.3.5-triazin (VII) und 3.6-Diphenyl-1.2.4.5-tetrazin (VIII) neben Stickstoff und Stickstoffwasser-stoffsaure in verschiedenem Verhaltnis; die Wechselbeziehungen dieser Produkte werden untersucht. Beim Zerfall des 5-Phenyl-tetrazols in primaren Aminen oder aromatischen Nitrilen werden die Losungsmittel teilweise in die Produkte eingebaut. Die Mechanismen der mannifaltigen Reaktionsablaufe, insbesondere die Bedeutung des C-Phenyl-nitrilimins (IV), werden diskutiert.
Top-30
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1 publication, 2.56%
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1 publication, 2.56%
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1 publication, 2.56%
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1 publication, 2.56%
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1 publication, 2.56%
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1 publication, 2.56%
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1 publication, 2.56%
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1 publication, 2.56%
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1 publication, 2.56%
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1
2
3
4
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Citations by publishers
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2
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14
16
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Elsevier
16 publications, 41.03%
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Wiley
15 publications, 38.46%
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2 publications, 5.13%
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Springer Nature
2 publications, 5.13%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.56%
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2
4
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8
10
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14
16
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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