Die Makromolekulare Chemie, volume 130, issue 1, pages 210-220
Copolymerization of carbon dioxide and epoxide with organometallic compounds
Publication type: Journal Article
Publication date: 1969-12-29
General Medicine
Abstract
Attempts to copolymerize carbon dioxide with epoxide led us to the first success in using carbon dioxide as a direct starting material for synthesizing high polymers. Some organometallic catalyst systems were found to catalyze the alternate copolymerization of carbon dioxide and epoxide, resulting in the formation of polycarbonates, the structures of which were confirmed with the aid of IR, NMR and elemental analysis. Diethylzinc-water system produced a methanol insoluble aliphatic polycarbonate of much higher molecular weight than that produced by polycondensation. Thermal properties of the methanol insoluble polycarbonate were studied by differential thermal analysis and thermogravimetric analysis.
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INOUE S., Koinuma H., Tsuruta T. Copolymerization of carbon dioxide and epoxide with organometallic compounds // Die Makromolekulare Chemie. 1969. Vol. 130. No. 1. pp. 210-220.
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INOUE S., Koinuma H., Tsuruta T. Copolymerization of carbon dioxide and epoxide with organometallic compounds // Die Makromolekulare Chemie. 1969. Vol. 130. No. 1. pp. 210-220.
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TY - JOUR
DO - 10.1002/macp.1969.021300112
UR - https://doi.org/10.1002/macp.1969.021300112
TI - Copolymerization of carbon dioxide and epoxide with organometallic compounds
T2 - Die Makromolekulare Chemie
AU - INOUE, SHOHEI
AU - Koinuma, Hideomi
AU - Tsuruta, Teiji
PY - 1969
DA - 1969/12/29
PB - Wiley
SP - 210-220
IS - 1
VL - 130
SN - 0025-116X
ER -
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@article{1969_INOUE,
author = {SHOHEI INOUE and Hideomi Koinuma and Teiji Tsuruta},
title = {Copolymerization of carbon dioxide and epoxide with organometallic compounds},
journal = {Die Makromolekulare Chemie},
year = {1969},
volume = {130},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/macp.1969.021300112},
number = {1},
pages = {210--220},
doi = {10.1002/macp.1969.021300112}
}
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MLA
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INOUE, SHOHEI, et al. “Copolymerization of carbon dioxide and epoxide with organometallic compounds.” Die Makromolekulare Chemie, vol. 130, no. 1, Dec. 1969, pp. 210-220. https://doi.org/10.1002/macp.1969.021300112.