Die Makromolekulare Chemie, volume 141, issue 1, pages 161-176
Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques
1
Institut Français du Pétrole, 92 Rueil-Malmaison France
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Publication type: Journal Article
Publication date: 1971-02-09
Journal:
Die Makromolekulare Chemie
Quartile SCImago
— Quartile WOS
—
Impact factor: —
ISSN: 0025116X, 0025116X
General Medicine
Abstract
La co-reaction des olefines cycliques avec les olefines acycliques en presence des systemes WOCl4/Al(C2H5)2Cl et WOCl4/Sn(C4H9)4 conduit a une telomerisation de l'olefine cyclique; aux extremites des molecules de telomere sont fixes deux groupements, identiques ou differents, issus de l'olefine acyclique par une reaction non consecutive.
Ont ete plus particulierement etudies: le cyclopentene et le cyclooctene d'une part, le pentene-2, le pentene-1, le butene-2 et le propylene d'autre part.
Le cyclooctadiene-1.5 et le cyclododecatriene-1.5.9 reagissent avec le pentene-2, par reaction non consecutive, en tant que reste CHCH2CH2CH.
La repartition des telomeres obeit a une loi statistique.
On propose un schema reactionnel en accord avec les faits observes dans la reaction de disproportion des olefines acycliques, la polymerisation des olefines cycliques et la telomerisation des olefines cycliques par les olefines acycliques.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Jean Louis Hérisson P., Chauvin Y. Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques // Die Makromolekulare Chemie. 1971. Vol. 141. No. 1. pp. 161-176.
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Jean Louis Hérisson P., Chauvin Y. Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques // Die Makromolekulare Chemie. 1971. Vol. 141. No. 1. pp. 161-176.
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TY - JOUR
DO - 10.1002/macp.1971.021410112
UR - https://doi.org/10.1002/macp.1971.021410112
TI - Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques
T2 - Die Makromolekulare Chemie
AU - Jean Louis Hérisson, Par
AU - Chauvin, Yves
PY - 1971
DA - 1971/02/09 00:00:00
PB - Wiley
SP - 161-176
IS - 1
VL - 141
SN - 0025-116X
SN - 0025-116X
ER -
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@article{1971_Jean Louis Hérisson,
author = {Par Jean Louis Hérisson and Yves Chauvin},
title = {Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques},
journal = {Die Makromolekulare Chemie},
year = {1971},
volume = {141},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/macp.1971.021410112},
number = {1},
pages = {161--176},
doi = {10.1002/macp.1971.021410112}
}
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MLA
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Jean Louis Hérisson, Par, and Yves Chauvin. “Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques.” Die Makromolekulare Chemie, vol. 141, no. 1, Feb. 1971, pp. 161-176. https://doi.org/10.1002/macp.1971.021410112.