Die Makromolekulare Chemie, volume 143, issue 1, pages 97-104

Stereochemistry of copolymerization of carbon dioxide with epoxycyclohexane

SHOHEI INOUE 1
Hideomi Koinuma 1
Yoshiharu Yokoo 1
Teiji Tsuruta 1
1
 
Department of Synthetic Chemistry Faculty of Engineering , University of Tokyo , Tokyo, Japan
Publication typeJournal Article
Publication date1971-04-01
Quartile SCImago
Quartile WOS
Impact factor
ISSN0025116X, 0025116X
General Medicine
Abstract
Copolymerization of carbon dioxide with 1.2-epoxycyclohexane (EPCH) and with 1.4-epoxycyclohexane was examined. 1.2-Epoxycyclohexane was copolymerized with carbon dioxide by the diethylzinc/water system, but 1.4-epoxycyclohexane was not polymerized by this catalyst. Determining the configuration of the EPCH unit in the EPCH/carbon dioxide copolymer by alkaline hydrolysis of the copolymer, it was found that the configuration at the carbon atom where ring opening of EPCH takes place was inverted during copolymerization.

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GOST |
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GOST Copy
INOUE S. et al. Stereochemistry of copolymerization of carbon dioxide with epoxycyclohexane // Die Makromolekulare Chemie. 1971. Vol. 143. No. 1. pp. 97-104.
GOST all authors (up to 50) Copy
INOUE S., Koinuma H., Yokoo Y., Tsuruta T. Stereochemistry of copolymerization of carbon dioxide with epoxycyclohexane // Die Makromolekulare Chemie. 1971. Vol. 143. No. 1. pp. 97-104.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/macp.1971.021430110
UR - https://doi.org/10.1002/macp.1971.021430110
TI - Stereochemistry of copolymerization of carbon dioxide with epoxycyclohexane
T2 - Die Makromolekulare Chemie
AU - INOUE, SHOHEI
AU - Koinuma, Hideomi
AU - Yokoo, Yoshiharu
AU - Tsuruta, Teiji
PY - 1971
DA - 1971/04/01 00:00:00
PB - Wiley
SP - 97-104
IS - 1
VL - 143
SN - 0025-116X
SN - 0025-116X
ER -
BibTex |
Cite this
BibTex Copy
@article{1971_INOUE,
author = {SHOHEI INOUE and Hideomi Koinuma and Yoshiharu Yokoo and Teiji Tsuruta},
title = {Stereochemistry of copolymerization of carbon dioxide with epoxycyclohexane},
journal = {Die Makromolekulare Chemie},
year = {1971},
volume = {143},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/macp.1971.021430110},
number = {1},
pages = {97--104},
doi = {10.1002/macp.1971.021430110}
}
MLA
Cite this
MLA Copy
INOUE, SHOHEI, et al. “Stereochemistry of copolymerization of carbon dioxide with epoxycyclohexane.” Die Makromolekulare Chemie, vol. 143, no. 1, Apr. 1971, pp. 97-104. https://doi.org/10.1002/macp.1971.021430110.
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