Complex formation of pyridine-azacrown ether amide macrocycles with proton and heavy metal ions in aqueous solution
Yury V Fedorov
1, 2
,
О. С. Федорова
1, 3
,
A. S. Peregudov
1
,
Stepan N. Kalmykov
2, 4
,
B. V. Egorova
2
,
Dmitry Arkhipov
1
,
Maxim Oshchepkov
1, 3
3
Publication type: Journal Article
Publication date: 2015-12-22
scimago Q3
wos Q3
SJR: 0.318
CiteScore: 4.1
Impact factor: 1.8
ISSN: 08943230, 10991395
DOI:
10.1002/poc.3526
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
This research concerns the analysis of the proton and metal ion binding of amide macrocycles of different structures and sizes by potentiometric, 1H NMR and X-ray diffraction methods. Protonated ligands exist as a 3D network structures. The ligands form 1:1 complexes with heavy metal ions (Cu2+, Cd2+, Pb2+, Zn2+, and Ni2+) in aqueous solutions and demonstrate the high selectivity towards Cu2+ cations. The pyridine-2,6-dicarbamide fragment provides structural rigidity to crown ether, resulting the molecule has an open cavity and faster kinetics of metal complexes formation. Copyright © 2015 John Wiley & Sons, Ltd.
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14
Total citations:
14
Citations from 2024:
4
(28%)
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GOST
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Fedorov Y. V. et al. Complex formation of pyridine-azacrown ether amide macrocycles with proton and heavy metal ions in aqueous solution // Journal of Physical Organic Chemistry. 2015. Vol. 29. No. 5. pp. 244-250.
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Fedorov Y. V., Федорова О. С., Peregudov A. S., Kalmykov S. N., Egorova B. V., Arkhipov D., Zubenko A., Oshchepkov M. Complex formation of pyridine-azacrown ether amide macrocycles with proton and heavy metal ions in aqueous solution // Journal of Physical Organic Chemistry. 2015. Vol. 29. No. 5. pp. 244-250.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/poc.3526
UR - https://doi.org/10.1002/poc.3526
TI - Complex formation of pyridine-azacrown ether amide macrocycles with proton and heavy metal ions in aqueous solution
T2 - Journal of Physical Organic Chemistry
AU - Fedorov, Yury V
AU - Федорова, О. С.
AU - Peregudov, A. S.
AU - Kalmykov, Stepan N.
AU - Egorova, B. V.
AU - Arkhipov, Dmitry
AU - Zubenko, Anastasia
AU - Oshchepkov, Maxim
PY - 2015
DA - 2015/12/22
PB - Wiley
SP - 244-250
IS - 5
VL - 29
SN - 0894-3230
SN - 1099-1395
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Fedorov,
author = {Yury V Fedorov and О. С. Федорова and A. S. Peregudov and Stepan N. Kalmykov and B. V. Egorova and Dmitry Arkhipov and Anastasia Zubenko and Maxim Oshchepkov},
title = {Complex formation of pyridine-azacrown ether amide macrocycles with proton and heavy metal ions in aqueous solution},
journal = {Journal of Physical Organic Chemistry},
year = {2015},
volume = {29},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/poc.3526},
number = {5},
pages = {244--250},
doi = {10.1002/poc.3526}
}
Cite this
MLA
Copy
Fedorov, Yury V., et al. “Complex formation of pyridine-azacrown ether amide macrocycles with proton and heavy metal ions in aqueous solution.” Journal of Physical Organic Chemistry, vol. 29, no. 5, Dec. 2015, pp. 244-250. https://doi.org/10.1002/poc.3526.