5-Amino-3,4-dinitropyrazole as a Promising Energetic Material
Nikita Muravyev
1
,
Anatoly A Bragin
1
,
Anna S Nikiforova
1
,
Igor V. Fomenkov
3
,
Nikolay I Shishov
4
,
2
4
Soyuz Federal Center of Dual-Use Technologies; Dzerzhinskii Russia
|
Publication type: Journal Article
Publication date: 2016-07-22
scimago Q2
wos Q3
SJR: 0.461
CiteScore: 3.9
Impact factor: 2.0
ISSN: 07213115, 15214087
General Chemistry
General Chemical Engineering
Abstract
The nitrogen-rich energetic compound 5-amino-3,4-dinitropyrazole (5-ADP) was investigated using complementary experimental techniques. X-ray diffraction indicates the strong intermolecular hydrogen bonding in 5-ADP crystals. Compound exhibits low impact sensitivity (23 J) and insensitivity to friction. The activation energy of thermolysis determined to be 230±5 kJ mol−1 from DSC measurements. Accelerating rate calorimetry indicates the lower thermal stability (173 °C) of 5-ADP than that of RDX, which is probably the main concern about using this compound. 5-ADP also exhibits good compatibility with common energetic materials (viz. TNT, RDX, ammonium perchlorate), including an active binder. The burning rate of 5-ADP monopropellant is higher than that of benchmark HMX, while the pressure exponent 0.51±0.04 is surprisingly low. Addition of ammonium perchlorate does not affect the pressure exponent of 5-ADP, while the burning rate increases. The 5-amino-3,4-dinitropyrazole exhibits a notable combination of combustion performance, low sensitivity, and good compatibility, which renders it as a promising energetic material.
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Total citations:
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Citations from 2025:
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(19.36%)
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GOST
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Muravyev N. et al. 5-Amino-3,4-dinitropyrazole as a Promising Energetic Material // Propellants, Explosives, Pyrotechnics. 2016. Vol. 41. No. 6. pp. 999-1005.
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Muravyev N., Bragin A. A., Monogarov K., Nikiforova A. S., Korlyukov A., Fomenkov I. V., Shishov N. I., Pivkina A. 5-Amino-3,4-dinitropyrazole as a Promising Energetic Material // Propellants, Explosives, Pyrotechnics. 2016. Vol. 41. No. 6. pp. 999-1005.
Cite this
RIS
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TY - JOUR
DO - 10.1002/prep.201600068
UR - https://doi.org/10.1002/prep.201600068
TI - 5-Amino-3,4-dinitropyrazole as a Promising Energetic Material
T2 - Propellants, Explosives, Pyrotechnics
AU - Muravyev, Nikita
AU - Bragin, Anatoly A
AU - Monogarov, Konstantin
AU - Nikiforova, Anna S
AU - Korlyukov, Alexander
AU - Fomenkov, Igor V.
AU - Shishov, Nikolay I
AU - Pivkina, Alla
PY - 2016
DA - 2016/07/22
PB - Wiley
SP - 999-1005
IS - 6
VL - 41
SN - 0721-3115
SN - 1521-4087
ER -
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BibTex (up to 50 authors)
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@article{2016_Muravyev,
author = {Nikita Muravyev and Anatoly A Bragin and Konstantin Monogarov and Anna S Nikiforova and Alexander Korlyukov and Igor V. Fomenkov and Nikolay I Shishov and Alla Pivkina},
title = {5-Amino-3,4-dinitropyrazole as a Promising Energetic Material},
journal = {Propellants, Explosives, Pyrotechnics},
year = {2016},
volume = {41},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/prep.201600068},
number = {6},
pages = {999--1005},
doi = {10.1002/prep.201600068}
}
Cite this
MLA
Copy
Muravyev, Nikita, et al. “5-Amino-3,4-dinitropyrazole as a Promising Energetic Material.” Propellants, Explosives, Pyrotechnics, vol. 41, no. 6, Jul. 2016, pp. 999-1005. https://doi.org/10.1002/prep.201600068.