volume 2 issue 25 pages 7508-7513

4-Diazo and 4-(Triaz-1-en-1-yl)-1H-pyrrole-2-carboxylates as Agents Inducing Apoptosis

Igor Kudryavtsev 2
Igor V. Kudryavtsev 2
Maxim A Terpilowski 3
Maria K Serebriakova 4
Andrey S Trulioff 5
Nikolay P. Goncharov 3, 6
Nikolay V Goncharov 3, 6
Publication typeJournal Article
Publication date2017-08-31
scimago Q3
wos Q3
SJR0.366
CiteScore3.0
Impact factor2.0
ISSN23656549
General Chemistry
Abstract
New β-diazopyrrole and β-triazenylpyrrole derivatives were synthesized from isoxazoles and pyridinium salts in two and three steps, respectively. The apoptotic/necrotic difference for these compounds was estimated on THP-1 cell line. The most effective of the panel is methyl 3-diazo-2-(2,4-dimethylphenyl)-4-phenyl-3H-pyrrole-5-carboxylate which demonstrated cytotoxic activity from the lowest concentration of 3.3 μM with a steep rise of the apoptotic effect and the largest apoptotic/necrotic difference within the range of 3.3 to 33 μM. Moreover, this diazopyrrole showed the highest sum total of apoptotic and necrotic AUCs within the same low range of concentrations. Methyl 2-(4-bromophenyl)-3-diazo-4-(3-methoxyphenyl)-3H-pyrrole-5-carboxylate and methyl 5-(4-bromophenyl)-3-(3-methoxyphenyl)-4-(piperidin-1-yl/morpholin-4-yldiazenyl)-1H-pyrrole-2-carboxylates were found to be quite promising compounds which deserve further cytophysiological and mechanistic research using different cell lines.
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Galenko E. E. et al. 4-Diazo and 4-(Triaz-1-en-1-yl)-1H-pyrrole-2-carboxylates as Agents Inducing Apoptosis // ChemistrySelect. 2017. Vol. 2. No. 25. pp. 7508-7513.
GOST all authors (up to 50) Copy
Galenko E. E., Galenko A. V., Novikov M. S., Khlebnikov A. F., Kudryavtsev I., Kudryavtsev I. V., Terpilowski M. A., Serebriakova M. K., Trulioff A. S., Goncharov N. P., Goncharov N. V. 4-Diazo and 4-(Triaz-1-en-1-yl)-1H-pyrrole-2-carboxylates as Agents Inducing Apoptosis // ChemistrySelect. 2017. Vol. 2. No. 25. pp. 7508-7513.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/slct.201701538
UR - https://onlinelibrary.wiley.com/doi/10.1002/slct.201701538
TI - 4-Diazo and 4-(Triaz-1-en-1-yl)-1H-pyrrole-2-carboxylates as Agents Inducing Apoptosis
T2 - ChemistrySelect
AU - Galenko, Ekaterina E
AU - Galenko, Alexey V
AU - Novikov, Mikhail S.
AU - Khlebnikov, Alexander F
AU - Kudryavtsev, Igor
AU - Kudryavtsev, Igor V.
AU - Terpilowski, Maxim A
AU - Serebriakova, Maria K
AU - Trulioff, Andrey S
AU - Goncharov, Nikolay P.
AU - Goncharov, Nikolay V
PY - 2017
DA - 2017/08/31
PB - Wiley
SP - 7508-7513
IS - 25
VL - 2
SN - 2365-6549
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2017_Galenko,
author = {Ekaterina E Galenko and Alexey V Galenko and Mikhail S. Novikov and Alexander F Khlebnikov and Igor Kudryavtsev and Igor V. Kudryavtsev and Maxim A Terpilowski and Maria K Serebriakova and Andrey S Trulioff and Nikolay P. Goncharov and Nikolay V Goncharov},
title = {4-Diazo and 4-(Triaz-1-en-1-yl)-1H-pyrrole-2-carboxylates as Agents Inducing Apoptosis},
journal = {ChemistrySelect},
year = {2017},
volume = {2},
publisher = {Wiley},
month = {aug},
url = {https://onlinelibrary.wiley.com/doi/10.1002/slct.201701538},
number = {25},
pages = {7508--7513},
doi = {10.1002/slct.201701538}
}
MLA
Cite this
MLA Copy
Galenko, Ekaterina E., et al. “4-Diazo and 4-(Triaz-1-en-1-yl)-1H-pyrrole-2-carboxylates as Agents Inducing Apoptosis.” ChemistrySelect, vol. 2, no. 25, Aug. 2017, pp. 7508-7513. https://onlinelibrary.wiley.com/doi/10.1002/slct.201701538.