ChemistrySelect, volume 5, issue 38, pages 11896-11900
Mechanistic Insights into the Synthesis of Telluride Colloidal Quantum Dots with Trioctylphosphine-Tellurium
Ivan A Shuklov
1, 2
,
Igor S Mikhel
3
,
Alexander V Nevidimov
4, 5
,
Kirill P. Birin
3
,
Natalia V. Dubrovina
6, 7
,
Anna A. Lizunova
1
,
Vladimir F. Razumov
1, 2, 3, 8
3
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences Leninsky Prospect 31/4 119071 Moscow Russia
|
4
Institute of Problems of Chemical Physics Russian Academy of Sciences Ac. Semenov avenue 1 142432 Chernogolovka Russia
|
5
Institute of Problems of Chemical Physics Russian Academy of Sciences Ac. Semenov avenue 1 142432 Chernogolovka Russia
|
8
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences Leninsky Prospect 31/4 119071 Moscow Russia
|
Publication type: Journal Article
Publication date: 2020-10-13
General Chemistry
Abstract
The combined NMR and quantum chemical study of tellurium solution in trioctylphosphine, for the first time, revealed the new unexpected P−Te species. The observed intermediates are absolutely different from the species forming in the reaction of trialkylphosphines with chalcogens up in the group. This finding sheds new light on the mechanism of telluride nanocrystals formation and allow to rationalize the application of this key tellurium precursor in the synthesis of nanostructures. The studied solution was applied in the synthesis of HgTe colloidal quantum dots.
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Shuklov I. A. et al. Mechanistic Insights into the Synthesis of Telluride Colloidal Quantum Dots with Trioctylphosphine-Tellurium // ChemistrySelect. 2020. Vol. 5. No. 38. pp. 11896-11900.
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Shuklov I. A., Mikhel I. S., Nevidimov A. V., Birin K. P., Dubrovina N. V., Lizunova A. A., Razumov V. F. Mechanistic Insights into the Synthesis of Telluride Colloidal Quantum Dots with Trioctylphosphine-Tellurium // ChemistrySelect. 2020. Vol. 5. No. 38. pp. 11896-11900.
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TY - JOUR
DO - 10.1002/slct.202002711
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202002711
TI - Mechanistic Insights into the Synthesis of Telluride Colloidal Quantum Dots with Trioctylphosphine-Tellurium
T2 - ChemistrySelect
AU - Shuklov, Ivan A
AU - Mikhel, Igor S
AU - Nevidimov, Alexander V
AU - Birin, Kirill P.
AU - Dubrovina, Natalia V.
AU - Lizunova, Anna A.
AU - Razumov, Vladimir F.
PY - 2020
DA - 2020/10/13
PB - Wiley
SP - 11896-11900
IS - 38
VL - 5
SN - 2365-6549
ER -
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BibTex (up to 50 authors)
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@article{2020_Shuklov,
author = {Ivan A Shuklov and Igor S Mikhel and Alexander V Nevidimov and Kirill P. Birin and Natalia V. Dubrovina and Anna A. Lizunova and Vladimir F. Razumov},
title = {Mechanistic Insights into the Synthesis of Telluride Colloidal Quantum Dots with Trioctylphosphine-Tellurium},
journal = {ChemistrySelect},
year = {2020},
volume = {5},
publisher = {Wiley},
month = {oct},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202002711},
number = {38},
pages = {11896--11900},
doi = {10.1002/slct.202002711}
}
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Shuklov, Ivan A., et al. “Mechanistic Insights into the Synthesis of Telluride Colloidal Quantum Dots with Trioctylphosphine-Tellurium.” ChemistrySelect, vol. 5, no. 38, Oct. 2020, pp. 11896-11900. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202002711.
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