Wiley
ChemistrySelect
,  volume 5 ,  issue 41 ,  pages 12829-12834

The first example of 3d-4f-heterometallic carboxylate complex containing phosphine ligand

Publication type: Journal Article
Publication date: 2020-10-30
Wiley
scimago Q3
wos Q3
SJR: 0.366
CiteScore: 3.0
Impact factor: 2.0
ISSN: 23656549
General Chemistry
Abstract

The interaction of heterometallic compounds [Co2La(Piv)6(NO3)(MeCN)2] (1) and [Co2La(Piv)6(NO3)(Py)2] (2) (Piv‐pivalate, Py‐pyridine) with triphenylphosphine was studied. It was shown that labile terminal molecules of MeCN in complex 1 were substituted by triphenylphosphine that led to the formation of complex [Co2La(Piv)6(NO3)(Ph3P)2] (3), whereas compound 2 in similar conditions did not undergo ligand substitution reaction. Molecular structure of compound 3 was determined by means single crystal X‐ray diffraction. The temperature dependence of the magnetic susceptibility of 3 was simulated with a model which implied only zero‐field splitting of Co(II) ions. It was found that ZFS parameters (D) for Co(II) ions in 3 were close to D value in 1. The field‐induced slow magnetic relaxation was observed for compound 3 on the result of magnetic susceptibility measurements in alternating current magnetic field.

Found 
Found 
7 citations
Eremenko Igor
DSc in Chemistry, professor, full member of the Russian Academy of Sciences 
674 publications,  7 718 citations,  29 reviews
h-index: 35
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
7 citations
Kiskin Mikhail
🥼 🤝
DSc in Chemistry, professor
407 publications,  5 037 citations
h-index: 31
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Research interests
Magnets
Nanoparticles
4 citations
Shmelev Maksim
🥼 🤝
PhD in Chemistry
95 publications,  753 citations
h-index: 16
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
4 citations
Yambulatov Dmitriy
🥼
PhD in Chemistry
43 publications,  454 citations,  256 reviews
h-index: 14
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Research interests
Coordination chemistry
Molecular magnetism
Phase transformations in materials
Redox isomerism
Redox-active ligands
3 citations
Rubtsova Irina
7 publications,  42 citations
h-index: 3
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Research interests
Coordination Chemistry
Molecular magnetism
1 citation
Ivanov Vladimir
🥼
DSc in Chemistry, full member of the Russian Academy of Sciences 
511 publications,  6 728 citations,  137 reviews
h-index: 37
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Lomonosov Moscow State University
Lomonosov Moscow State University
National Research University Higher School of Economics
National Research University Higher School of Economics
Research interests
Cerium
Functional materials
Materials Science
Nanomaterials
Nanosimes
Rare-earth elements
Solid state chemistry
1 citation
Voronina Julia
131 publications,  1 116 citations
h-index: 18
Plekhanov Russian University of Economics
Plekhanov Russian University of Economics
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
1 citation
Korchagin Denis
PhD in Chemistry
149 publications,  1 519 citations
h-index: 20
Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS
Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS
Research interests
Coordination Chemistry
Monomolecular magnets
Quantum Chemistry
Spin transitions
X-ray diffraction (XRD)
1 citation
Khamatgalimov Ayrat
DSc in Chemistry
90 publications,  887 citations
h-index: 17
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
1 citation
Goloveshkin Alexander
🥼 🤝
PhD in Chemistry
145 publications,  1 923 citations
h-index: 24
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
2D Materials
Crystallography
Electrocatalysis
Nanomaterials
Non-valent interactions
Quantum Chemistry
X-ray diffraction (XRD)
1 citation
Bushuev Vladimir
5 publications,  8 citations
h-index: 1
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
National Research University Higher School of Economics
National Research University Higher School of Economics
Research interests
Coordination Chemistry
Molecular switches

Top-30

Journals

1
2
3
4
5
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 5, 35.71%
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
5 publications, 35.71%
Координационная химия
Координационная химия, 3, 21.43%
Координационная химия
3 publications, 21.43%
Mendeleev Communications, 1, 7.14%
Mendeleev Communications
1 publication, 7.14%
ChemistrySelect
ChemistrySelect, 1, 7.14%
ChemistrySelect
1 publication, 7.14%
New Journal of Chemistry
New Journal of Chemistry, 1, 7.14%
New Journal of Chemistry
1 publication, 7.14%
Russian Chemical Bulletin
Russian Chemical Bulletin, 1, 7.14%
Russian Chemical Bulletin
1 publication, 7.14%
Molecules
Molecules, 1, 7.14%
Molecules
1 publication, 7.14%
Journal of Cluster Science
Journal of Cluster Science, 1, 7.14%
Journal of Cluster Science
1 publication, 7.14%
1
2
3
4
5

Publishers

1
2
3
4
5
6
7
8
Pleiades Publishing
Pleiades Publishing, 8, 57.14%
Pleiades Publishing
8 publications, 57.14%
Springer Nature
Springer Nature, 2, 14.29%
Springer Nature
2 publications, 14.29%
OOO Zhurnal "Mendeleevskie Soobshcheniya", 1, 7.14%
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 7.14%
Wiley
Wiley, 1, 7.14%
Wiley
1 publication, 7.14%
Royal Society of Chemistry (RSC)
Royal Society of Chemistry (RSC), 1, 7.14%
Royal Society of Chemistry (RSC)
1 publication, 7.14%
MDPI
MDPI, 1, 7.14%
MDPI
1 publication, 7.14%
1
2
3
4
5
6
7
8
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
14
Share
Cite this
GOST |
Cite this
GOST Copy
Nikolaevskii S. A. et al. The first example of 3d-4f-heterometallic carboxylate complex containing phosphine ligand // ChemistrySelect. 2020. Vol. 5. No. 41. pp. 12829-12834.
GOST all authors (up to 50) Copy
Nikolaevskii S. A., Yambulatov D. S., Voronina J. K., Melnikov S. N., Babeshkin K. A., Efimov N. N., Goloveshkin A. S., Kiskin M. A., Sidorov A., Eremenko I. L. The first example of 3d-4f-heterometallic carboxylate complex containing phosphine ligand // ChemistrySelect. 2020. Vol. 5. No. 41. pp. 12829-12834.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/slct.202002982
UR - https://doi.org/10.1002/slct.202002982
TI - The first example of 3d-4f-heterometallic carboxylate complex containing phosphine ligand
T2 - ChemistrySelect
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Yambulatov, Dmitriy S
AU - Voronina, Julia K.
AU - Melnikov, Stanislav N
AU - Babeshkin, Konstantin A
AU - Efimov, Nikolay N.
AU - Goloveshkin, Alexander S.
AU - Kiskin, Mikhail A.
AU - Sidorov, A.V
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/10/30
PB - Wiley
SP - 12829-12834
IS - 41
VL - 5
SN - 2365-6549
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Nikolaevskii,
author = {Stanislav Alexandrovich Nikolaevskii and Dmitriy S Yambulatov and Julia K. Voronina and Stanislav N Melnikov and Konstantin A Babeshkin and Nikolay N. Efimov and Alexander S. Goloveshkin and Mikhail A. Kiskin and A.V Sidorov and Igor L. Eremenko},
title = {The first example of 3d-4f-heterometallic carboxylate complex containing phosphine ligand},
journal = {ChemistrySelect},
year = {2020},
volume = {5},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/slct.202002982},
number = {41},
pages = {12829--12834},
doi = {10.1002/slct.202002982}
}
MLA
Cite this
MLA Copy
Nikolaevskii, Stanislav Alexandrovich, et al. “The first example of 3d-4f-heterometallic carboxylate complex containing phosphine ligand.” ChemistrySelect, vol. 5, no. 41, Oct. 2020, pp. 12829-12834. https://doi.org/10.1002/slct.202002982.