Wiley
ChemistrySelect
,  volume 6 ,  issue 39 ,  pages 10609-10618

Catechol‐ and Phenol‐Containing Thio‐Schiff Bases: Synthesis, Electrochemical Properties and Biological Evaluation

Ivan V. Smolyaninov 1
, 
Daria A. Burmistrova 1
, 
Maxim V Arsenyev 2
, 
Nailya R Almyasheva 3
, 
Ekaterina S Ivanova 4
, 
Susanna A Smolyaninova 1
, 
Konstantin P Pashchenko 5
, 
Andrey I. Poddel'sky 2
, 
N. T. Berberova 5
, 
Nadezhda T. Berberova 1
1
 
2
 
3
 
4
 
5
 
Publication type: Journal Article
Publication date: 2021-10-18
Wiley
scimago Q3
wos Q3
SJR: 0.366
CiteScore: 3.0
Impact factor: 2.0
ISSN: 23656549
General Chemistry
Abstract

A number of novel catechol‐ and phenol‐containing Schiff bases with thiophenol or mercaptobenzimidazole groups have been synthesized. Electrochemical studies of the target compounds were carried out in order to establish the primary centres involved in redox reactions, and the mechanism of oxidative transformations. The antioxidant activities of the compounds were determined using different assays. Compounds combining the catechol group with the mercaptobenzimidazole or benzothiazoline cycles exhibit more pronounced antioxidant activity in the concerning tests. However, a significant promoting effect on the process of lipid peroxidation of rat brain homogenates was found in the presence of catechols. Antibacterial and cytotoxic effects of Schiff bases can be caused by the possibility of ROS and o‐benzoquinones generation. It was established that some compounds have a moderate bacteriostatic effect against Staphylococcus aureus strains. Schiff bases with catechol and heterocyclic groups exhibit a good antiproliferative activity (IC50<10 μM) towards MCF‐7, HTC‐116 and A549 cell lines.

Found 
Found 
5 citations
Smolyaninov Ivan
DSc in Chemistry
107 publications,  1 339 citations,  1 review
h-index: 20
Astrakhan State Technical University
Astrakhan State Technical University
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Research interests
Electrochemistry
5 citations
Burmistrova Daria
PhD in Chemistry
28 publications,  163 citations
h-index: 9
Astrakhan State Technical University
Astrakhan State Technical University
3 citations
Eremenko Igor
DSc in Chemistry, professor, full member of the Russian Academy of Sciences 
674 publications,  7 751 citations,  29 reviews
h-index: 35
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
3 citations
Voronina Julia
131 publications,  1 130 citations
h-index: 18
Plekhanov Russian University of Economics
Plekhanov Russian University of Economics
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
3 citations
Arsenyev Maxim
🥼 🤝
PhD in Chemistry, associate professor
94 publications,  812 citations,  2 reviews
h-index: 17
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Lobachevsky State University of Nizhny Novgorod
Lobachevsky State University of Nizhny Novgorod
Research interests
Chemistry of high molecular weight compounds
Electrochemistry
Organic chemistry
Organic electrochemistry
Photopolymerization
2 citations
Zherebtsov Maxim
PhD in Chemistry
10 publications,  34 citations
h-index: 4
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Lobachevsky State University of Nizhny Novgorod
Lobachevsky State University of Nizhny Novgorod
Research interests
Organic Chemistry
Organometallic Chemistry
2 citations
Chesnokov Sergey
🥼
DSc in Chemistry
153 publications,  1 144 citations,  1 review
h-index: 18
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Research interests
3D printing
Biomaterials
Photopolymerization
Porous materials
2 citations
Baranov Evgeniy
PhD in Chemistry
247 publications,  3 241 citations
h-index: 29
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Research interests
Crystal Chemistry
Organic Chemistry
Organometallic Chemistry
Quantum Chemistry
X-ray diffraction analysis
1 citation
Ananyev Ivan
DSc in Physics and Mathematics
169 publications,  2 904 citations,  19 reviews
h-index: 30
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
National Research University Higher School of Economics
National Research University Higher School of Economics
Research interests
Crystal Chemistry
Physical Chemistry
Quantum Chemistry

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Smolyaninov I. V. et al. Catechol‐ and Phenol‐Containing Thio‐Schiff Bases: Synthesis, Electrochemical Properties and Biological Evaluation // ChemistrySelect. 2021. Vol. 6. No. 39. pp. 10609-10618.
GOST all authors (up to 50) Copy
Smolyaninov I. V., Burmistrova D. A., Arsenyev M. V., Almyasheva N. R., Ivanova E. S., Smolyaninova S. A., Pashchenko K. P., Poddel'sky A. I., Berberova N. T., Berberova N. T. Catechol‐ and Phenol‐Containing Thio‐Schiff Bases: Synthesis, Electrochemical Properties and Biological Evaluation // ChemistrySelect. 2021. Vol. 6. No. 39. pp. 10609-10618.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/slct.202102246
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202102246
TI - Catechol‐ and Phenol‐Containing Thio‐Schiff Bases: Synthesis, Electrochemical Properties and Biological Evaluation
T2 - ChemistrySelect
AU - Smolyaninov, Ivan V.
AU - Burmistrova, Daria A.
AU - Arsenyev, Maxim V
AU - Almyasheva, Nailya R
AU - Ivanova, Ekaterina S
AU - Smolyaninova, Susanna A
AU - Pashchenko, Konstantin P
AU - Poddel'sky, Andrey I.
AU - Berberova, N. T.
AU - Berberova, Nadezhda T.
PY - 2021
DA - 2021/10/18
PB - Wiley
SP - 10609-10618
IS - 39
VL - 6
SN - 2365-6549
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Smolyaninov,
author = {Ivan V. Smolyaninov and Daria A. Burmistrova and Maxim V Arsenyev and Nailya R Almyasheva and Ekaterina S Ivanova and Susanna A Smolyaninova and Konstantin P Pashchenko and Andrey I. Poddel'sky and N. T. Berberova and Nadezhda T. Berberova},
title = {Catechol‐ and Phenol‐Containing Thio‐Schiff Bases: Synthesis, Electrochemical Properties and Biological Evaluation},
journal = {ChemistrySelect},
year = {2021},
volume = {6},
publisher = {Wiley},
month = {oct},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202102246},
number = {39},
pages = {10609--10618},
doi = {10.1002/slct.202102246}
}
MLA
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MLA Copy
Smolyaninov, Ivan V., et al. “Catechol‐ and Phenol‐Containing Thio‐Schiff Bases: Synthesis, Electrochemical Properties and Biological Evaluation.” ChemistrySelect, vol. 6, no. 39, Oct. 2021, pp. 10609-10618. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202102246.