Radical high polymerization of di-tert-butyl fumarate and novel synthesis of high molecular weight poly(fumaric acid) from its polymer
Publication type: Journal Article
Publication date: 1984-01-01
scimago Q2
wos Q2
SJR: 0.658
CiteScore: 6.7
Impact factor: 4.0
ISSN: 01700839, 14362449
Materials Chemistry
General Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
Di-tert-butyl fumarate (DtBF) was found to homopolymerize easily with 1,1′-azobisisobutyronitrile and benzoyl peroxide as radical initiators at 50~80°C to give a nonflexible rod-like polymer, poly(tert-butoxycarbonylmethylene) with number-average molecular weight of more than 100,000. The colorless powderlike polymer thus obtained was soluble in benzene, toluene, carbon tetrachloride and tetrahydrofuran, and gave a transparent film or fiber from its toluene solution. This polymer did not melt, but it underwent degradation with a quantitative elimination of isobutene at 180~190°C. The remaining polymer was confirmed to be a pure poly(fumaric acid), poly(hydroxycarbonylmethylene). Therefore, the degradation of poly(DtBF) in solution at 180~190°C was found to be a new route for synthesizing of a high molecular weight poly(fumaric acid).
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74
Total citations:
74
Citations from 2024:
13
(17%)
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GOST
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Otsu T. et al. Radical high polymerization of di-tert-butyl fumarate and novel synthesis of high molecular weight poly(fumaric acid) from its polymer // Polymer Bulletin. 1984. Vol. 12. No. 5.
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Otsu T., Yasuhara T., SHIRAISHI K., Mori S. Radical high polymerization of di-tert-butyl fumarate and novel synthesis of high molecular weight poly(fumaric acid) from its polymer // Polymer Bulletin. 1984. Vol. 12. No. 5.
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TY - JOUR
DO - 10.1007/bf00255433
UR - https://doi.org/10.1007/bf00255433
TI - Radical high polymerization of di-tert-butyl fumarate and novel synthesis of high molecular weight poly(fumaric acid) from its polymer
T2 - Polymer Bulletin
AU - Otsu, Takayuki
AU - Yasuhara, Takashi
AU - SHIRAISHI, Kohei
AU - Mori, Shigeki
PY - 1984
DA - 1984/01/01
PB - Springer Nature
IS - 5
VL - 12
SN - 0170-0839
SN - 1436-2449
ER -
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@article{1984_Otsu,
author = {Takayuki Otsu and Takashi Yasuhara and Kohei SHIRAISHI and Shigeki Mori},
title = {Radical high polymerization of di-tert-butyl fumarate and novel synthesis of high molecular weight poly(fumaric acid) from its polymer},
journal = {Polymer Bulletin},
year = {1984},
volume = {12},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/bf00255433},
number = {5},
doi = {10.1007/bf00255433}
}