On the isomerization of a trans-dichloro to a cis-dichloro amide-chelated ruthenium benzylidene complex and the catalytic scope of these species in olefin metathesis
Publication type: Journal Article
Publication date: 2012-03-23
scimago Q3
wos Q3
SJR: 0.321
CiteScore: 3.4
Impact factor: 1.9
ISSN: 00269247, 14344475
General Chemistry
Abstract
Upon comparative NMR spectroscopy studies, the isomerization of newly disclosed dichloro [κ2(C,O)-2-(N-propylaminocarbonyl)benzylidene][1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene]ruthenium from trans-dichloro configuration (SPY-5-31) to its thermodynamically more favored cis-dichloro derivative (with SPY-5-34 stereochemistry) was found to proceed via dissociation of one chloride ligand to form an intermediate cationic species. Furthermore, the performance of the trans- and the cis-dichloro derivatives as catalysts in ring-closing metathesis and as initiators in ring-opening metathesis polymerization was studied.
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Leitgeb A., Mereiter K., Slugovc C. On the isomerization of a trans-dichloro to a cis-dichloro amide-chelated ruthenium benzylidene complex and the catalytic scope of these species in olefin metathesis // Monatshefte fur Chemie. 2012. Vol. 143. No. 6. pp. 901-908.
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Leitgeb A., Mereiter K., Slugovc C. On the isomerization of a trans-dichloro to a cis-dichloro amide-chelated ruthenium benzylidene complex and the catalytic scope of these species in olefin metathesis // Monatshefte fur Chemie. 2012. Vol. 143. No. 6. pp. 901-908.
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TY - JOUR
DO - 10.1007/s00706-012-0740-6
UR - https://doi.org/10.1007/s00706-012-0740-6
TI - On the isomerization of a trans-dichloro to a cis-dichloro amide-chelated ruthenium benzylidene complex and the catalytic scope of these species in olefin metathesis
T2 - Monatshefte fur Chemie
AU - Leitgeb, Anita
AU - Mereiter, Kurt
AU - Slugovc, Christian
PY - 2012
DA - 2012/03/23
PB - Springer Nature
SP - 901-908
IS - 6
VL - 143
SN - 0026-9247
SN - 1434-4475
ER -
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BibTex (up to 50 authors)
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@article{2012_Leitgeb,
author = {Anita Leitgeb and Kurt Mereiter and Christian Slugovc},
title = {On the isomerization of a trans-dichloro to a cis-dichloro amide-chelated ruthenium benzylidene complex and the catalytic scope of these species in olefin metathesis},
journal = {Monatshefte fur Chemie},
year = {2012},
volume = {143},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s00706-012-0740-6},
number = {6},
pages = {901--908},
doi = {10.1007/s00706-012-0740-6}
}
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MLA
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Leitgeb, Anita, et al. “On the isomerization of a trans-dichloro to a cis-dichloro amide-chelated ruthenium benzylidene complex and the catalytic scope of these species in olefin metathesis.” Monatshefte fur Chemie, vol. 143, no. 6, Mar. 2012, pp. 901-908. https://doi.org/10.1007/s00706-012-0740-6.