Springer Nature
Journal of Radioanalytical and Nuclear Chemistry
,  volume 333 ,  issue 4 ,  pages 1927-1935

HNO3 extractability, distribution of macrocycle and radiation stability of strontium-selective extractant based on the dicyclohexano-18-crown-6 solution in 1,1,7-trihydrododecafluoroheptanol

Publication type: Journal Article
Publication date: 2024-02-14
Springer Nature
scimago Q2
wos Q3
SJR: 0.388
CiteScore: 2.9
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
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Nuclear Energy and Engineering
Radiology, Nuclear Medicine and imaging
Abstract
1,1,7-Trihydrododecafluoroheptanol is a promising solvent for the development of strontium-selective extractants based on individual stereoisomers of dicyclohexano-18-crown-6 (DCH18C6). In this study the distribution of DCH18C6 between organic and aqueous phases was determined and the effect of macrocycle stereoisomerism was revealed. Extractability of nitric acid depended on the acidity of initial aqueous phase and did not on DCH18C6 stereoisomerism. Based on the structure of radiolytic intermediates, the main channels of radiation destruction of the macrocycle and the solvent were proposed. The obtained data highlights the potentiality of the DCH18C6/1,1,7-trihydrododecafluoroheptanol for designing a technological process for the selective strontium extraction.
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Nesterov S. et al. HNO3 extractability, distribution of macrocycle and radiation stability of strontium-selective extractant based on the dicyclohexano-18-crown-6 solution in 1,1,7-trihydrododecafluoroheptanol // Journal of Radioanalytical and Nuclear Chemistry. 2024. Vol. 333. No. 4. pp. 1927-1935.
GOST all authors (up to 50) Copy
Nesterov S., Rychkov P. V., Zakurdaeva O. A., Feldman V. I. HNO3 extractability, distribution of macrocycle and radiation stability of strontium-selective extractant based on the dicyclohexano-18-crown-6 solution in 1,1,7-trihydrododecafluoroheptanol // Journal of Radioanalytical and Nuclear Chemistry. 2024. Vol. 333. No. 4. pp. 1927-1935.
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TY - JOUR
DO - 10.1007/s10967-024-09393-x
UR - https://link.springer.com/10.1007/s10967-024-09393-x
TI - HNO3 extractability, distribution of macrocycle and radiation stability of strontium-selective extractant based on the dicyclohexano-18-crown-6 solution in 1,1,7-trihydrododecafluoroheptanol
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Nesterov, Sergey
AU - Rychkov, P. V.
AU - Zakurdaeva, O A
AU - Feldman, V I
PY - 2024
DA - 2024/02/14
PB - Springer Nature
SP - 1927-1935
IS - 4
VL - 333
SN - 0236-5731
SN - 1588-2780
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2024_Nesterov,
author = {Sergey Nesterov and P. V. Rychkov and O A Zakurdaeva and V I Feldman},
title = {HNO3 extractability, distribution of macrocycle and radiation stability of strontium-selective extractant based on the dicyclohexano-18-crown-6 solution in 1,1,7-trihydrododecafluoroheptanol},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {2024},
volume = {333},
publisher = {Springer Nature},
month = {feb},
url = {https://link.springer.com/10.1007/s10967-024-09393-x},
number = {4},
pages = {1927--1935},
doi = {10.1007/s10967-024-09393-x}
}
MLA
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Nesterov, Sergey, et al. “HNO3 extractability, distribution of macrocycle and radiation stability of strontium-selective extractant based on the dicyclohexano-18-crown-6 solution in 1,1,7-trihydrododecafluoroheptanol.” Journal of Radioanalytical and Nuclear Chemistry, vol. 333, no. 4, Feb. 2024, pp. 1927-1935. https://link.springer.com/10.1007/s10967-024-09393-x.