Russian Chemical Bulletin, volume 53, issue 11, pages 2406-2427
Spin transitions in non-classical systems
Ovcharenko V.I.
1, 2
,
Maryunina K Yu
2
,
Fokin S V
1
,
Tretyakov E. V.
1
,
Romanenko G V
1
,
Ikorskii V. N.
1
Publication type: Journal Article
Publication date: 2004-11-01
Journal:
Russian Chemical Bulletin
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Abstract
Peculiarities of synthesis of chain polymeric, copper(II) hexafluoroacetylacetonate based complexes with stable nitroxyl radicals and the results of studies on correlations between the magnetic properties and structure of these compounds are summarized. Temperature variation causes structural rearrangements in the solid phases of the compounds, accompanied by the magnetic effects similar to spin crossover phenomena. Magnetic anomalies induced by phase transitions originate from specific motions in the Jahn—Teller coordination units containing two types of exchange clusters, Cu2+—O·—N< or >N—·O—Cu2+—O·—N<, and are accompanied by significant changes in the crystal volume after multiple cooling/heating cycles. Chemical methods of controlling the character and temperature of spin transitions by both the formation of solid solutions of mixed metal hexafluoroacetylacetonates with the same nitroxyl radical, {Cu1−xMx(hfac)2L} (M = Mn, Ni, Co), and by the formation of solid solutions based on copper(II) hexafluoroacetylacetonate with different nitroxyl radicals, {Cu(hfac)2LxL′1−x}, are discussed. Specific influence of isotope substitution CH3 → CD3 in the paramagnetic ligand on both the structure of the heterospin polymer chain and the temperature of the magnetic anomaly is discussed.
Citations by journals
Citations by publishers
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5
10
15
20
25
30
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American Chemical Society (ACS)
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American Chemical Society (ACS)
26 publications, 30.59%
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Pleiades Publishing
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Pleiades Publishing
11 publications, 12.94%
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Springer Nature
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Springer Nature
11 publications, 12.94%
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Elsevier
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Elsevier
11 publications, 12.94%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
9 publications, 10.59%
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Wiley
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Wiley
6 publications, 7.06%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 2.35%
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Taylor & Francis
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Taylor & Francis
2 publications, 2.35%
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American Physical Society (APS)
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American Physical Society (APS)
1 publication, 1.18%
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CSIRO Publishing
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CSIRO Publishing
1 publication, 1.18%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.18%
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IEEE
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IEEE
1 publication, 1.18%
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American Institute of Physics (AIP)
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American Institute of Physics (AIP)
1 publication, 1.18%
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5
10
15
20
25
30
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Ovcharenko V. et al. Spin transitions in non-classical systems // Russian Chemical Bulletin. 2004. Vol. 53. No. 11. pp. 2406-2427.
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Ovcharenko V., Maryunina K. Yu., Fokin S. V., Tretyakov E. V., Romanenko G. V., Ikorskii V. N. Spin transitions in non-classical systems // Russian Chemical Bulletin. 2004. Vol. 53. No. 11. pp. 2406-2427.
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TY - JOUR
DO - 10.1007/s11172-005-0136-4
UR - https://doi.org/10.1007%2Fs11172-005-0136-4
TI - Spin transitions in non-classical systems
T2 - Russian Chemical Bulletin
AU - Ovcharenko, V.I.
AU - Maryunina, K Yu
AU - Fokin, S V
AU - Tretyakov, E. V.
AU - Romanenko, G V
AU - Ikorskii, V. N.
PY - 2004
DA - 2004/11/01 00:00:00
PB - Springer Nature
SP - 2406-2427
IS - 11
VL - 53
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2004_Ovcharenko,
author = {V.I. Ovcharenko and K Yu Maryunina and S V Fokin and E. V. Tretyakov and G V Romanenko and V. N. Ikorskii},
title = {Spin transitions in non-classical systems},
journal = {Russian Chemical Bulletin},
year = {2004},
volume = {53},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007%2Fs11172-005-0136-4},
number = {11},
pages = {2406--2427},
doi = {10.1007/s11172-005-0136-4}
}
Cite this
MLA
Copy
Ovcharenko, V.I., et al. “Spin transitions in non-classical systems.” Russian Chemical Bulletin, vol. 53, no. 11, Nov. 2004, pp. 2406-2427. https://doi.org/10.1007%2Fs11172-005-0136-4.