Russian Chemical Bulletin

, volume 61 , issue 1 , pages 64-73

Diastereoselective synthesis of 4,5-dihydroxyimidazolidin-2-ones (-thiones) and their structure

A N Kravchenko ¹

V.V. Baranov ¹

Yu V Nelyubina ²

G A Gazieva ¹

I V Svitanko ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation |

A. N. Nesmeyanov Institute of Organoelement COmpounds, Russian Academy of Sciences, Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2012-01-01

Springer Nature

Russian Chemical Bulletin

scimago Q3

SJR: 0.305

CiteScore: 2.8

Impact factor: —

ISSN: 10665285, 15739171

DOI: 10.1007/s11172-012-0010-0

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General Chemistry

Abstract

Studies on the synthesis of 4,5-dihydroxyimidazolidin-2-ones (-thiones) based on the condensation of ureas or thioureas with glyoxal or 1,2-dioxo-1,2-diphenylethane showed high diastereoselectivity in the formation of racemates (trans-diastereomers) of 4,5-dihydroxyimidazolidin-2-ones (-thiones) and meso-forms (cis-diastereomers) of 4,5-dihydroxy-4,5-diphenyl-1,3-dialkylimidazolidine-2-thiones; plausible mechanisms of their formation were suggested. X-ray diffraction studies confirmed structures of diastereomers for separate examples of racemates and meso-forms of 4,5-dihydroxyimidazolidin-2-ones (-thiones).

Found

3 citations

Nelyubina Yulia

🤝

DSc in Chemistry

506 publications, 7 574 citations, 1 review

h-index: 38

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

Metal-organic frameworks

Quantum technologies

Sensors

1 citation

Fershtat Leonid

DSc in Chemistry

146 publications, 2 959 citations, 121 reviews

h-index: 29

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Izmest'ev Alexei

PhD in Chemistry

33 publications, 306 citations

h-index: 12

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Gazizov Almir

🥼

DSc in Chemistry

157 publications, 879 citations, 23 reviews

h-index: 14

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Heterocyclic compounds

Organic Chemistry

Organophosphorus chemistry

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Kravchenko A. N. et al. Diastereoselective synthesis of 4,5-dihydroxyimidazolidin-2-ones (-thiones) and their structure // Russian Chemical Bulletin. 2012. Vol. 61. No. 1. pp. 64-73.

GOST all authors (up to 50) Copy

Kravchenko A. N., Baranov V., Nelyubina Yu. V., Gazieva G. A., Svitanko I. V. Diastereoselective synthesis of 4,5-dihydroxyimidazolidin-2-ones (-thiones) and their structure // Russian Chemical Bulletin. 2012. Vol. 61. No. 1. pp. 64-73.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1007/s11172-012-0010-0

UR - http://link.springer.com/10.1007/s11172-012-0010-0

TI - Diastereoselective synthesis of 4,5-dihydroxyimidazolidin-2-ones (-thiones) and their structure

T2 - Russian Chemical Bulletin

AU - Kravchenko, A N

AU - Baranov, V.V.

AU - Nelyubina, Yu V

AU - Gazieva, G A

AU - Svitanko, I V

PY - 2012

DA - 2012/01/01

PB - Springer Nature

SP - 64-73

IS - 1

VL - 61

SN - 1066-5285

SN - 1573-9171

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2012_Kravchenko,

author = {A N Kravchenko and V.V. Baranov and Yu V Nelyubina and G A Gazieva and I V Svitanko},

title = {Diastereoselective synthesis of 4,5-dihydroxyimidazolidin-2-ones (-thiones) and their structure},

journal = {Russian Chemical Bulletin},

year = {2012},

volume = {61},

publisher = {Springer Nature},

month = {jan},

url = {http://link.springer.com/10.1007/s11172-012-0010-0},

number = {1},

pages = {64--73},

doi = {10.1007/s11172-012-0010-0}

}

MLA

Cite this

MLA Copy

Kravchenko, A. N., et al. “Diastereoselective synthesis of 4,5-dihydroxyimidazolidin-2-ones (-thiones) and their structure.” Russian Chemical Bulletin, vol. 61, no. 1, Jan. 2012, pp. 64-73. http://link.springer.com/10.1007/s11172-012-0010-0.

Publisher

Springer Nature

Journal

Russian Chemical Bulletin

scimago Q3

SJR

0.305

CiteScore

2.8

Impact factor

—

ISSN

10665285 (Print)

15739171 (Electronic)

Labs

Molecular Structure Research Center

Profiles