Synthesis, structure, and magnetic properties of the cobalt(ii) iodide complex with 1,4-diazabuta-1,3-diene ligand
Publication type: Journal Article
Publication date: 2021-12-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reaction of cobalt(ii) iodide with 1,4-bis(2,4,6-trimethylphenyl)-1,4-diazabuta-1,3-diene (Mes-DAD) in anhydrous acetonitrile afforded the mononuclear complex [CoI2(Mes-DAD)] (1). The crystal structure of the complex was established by single-crystal X-ray diffraction. The phase purity was confirmed by powder X-ray diffraction. The zero-field splitting parameter (D = 17.2 cm−1) and the intermolecular exchange coupling parameter (zJ = −0.78 cm−1) were determined from magnetochemical studies of complex 1 in a direct current magnetic field of 5 kOe in the temperature range of 2–300 K. Magnetic measurements in an alternating magnetic field showed the absence of slow relaxation of the magnetization.
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Total citations:
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Citations from 2024:
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Yambulatov D. S. et al. Synthesis, structure, and magnetic properties of the cobalt(ii) iodide complex with 1,4-diazabuta-1,3-diene ligand // Russian Chemical Bulletin. 2021. Vol. 70. No. 12. pp. 2390-2396.
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Yambulatov D. S., Nikolaevskii S. A., Babeshkin K. A., Efimov N. N., Kiskin M. A., Eremenko I. L. Synthesis, structure, and magnetic properties of the cobalt(ii) iodide complex with 1,4-diazabuta-1,3-diene ligand // Russian Chemical Bulletin. 2021. Vol. 70. No. 12. pp. 2390-2396.
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RIS
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TY - JOUR
DO - 10.1007/s11172-021-3358-1
UR - https://doi.org/10.1007/s11172-021-3358-1
TI - Synthesis, structure, and magnetic properties of the cobalt(ii) iodide complex with 1,4-diazabuta-1,3-diene ligand
T2 - Russian Chemical Bulletin
AU - Yambulatov, D S
AU - Nikolaevskii, S A
AU - Babeshkin, K A
AU - Efimov, N. N.
AU - Kiskin, M. A.
AU - Eremenko, I. L.
PY - 2021
DA - 2021/12/01
PB - Springer Nature
SP - 2390-2396
IS - 12
VL - 70
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2021_Yambulatov,
author = {D S Yambulatov and S A Nikolaevskii and K A Babeshkin and N. N. Efimov and M. A. Kiskin and I. L. Eremenko},
title = {Synthesis, structure, and magnetic properties of the cobalt(ii) iodide complex with 1,4-diazabuta-1,3-diene ligand},
journal = {Russian Chemical Bulletin},
year = {2021},
volume = {70},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/s11172-021-3358-1},
number = {12},
pages = {2390--2396},
doi = {10.1007/s11172-021-3358-1}
}
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MLA
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Yambulatov, D. S., et al. “Synthesis, structure, and magnetic properties of the cobalt(ii) iodide complex with 1,4-diazabuta-1,3-diene ligand.” Russian Chemical Bulletin, vol. 70, no. 12, Dec. 2021, pp. 2390-2396. https://doi.org/10.1007/s11172-021-3358-1.