Synthesis and structure of copper(ii) and manganese(ii) diethylmalonates with 4,4′-bipyridine
Publication type: Journal Article
Publication date: 2024-10-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
Abstract
Two new mixed-ligand 3d-metal (MnII, CuII) coordination compounds with diethylmalonate anions and 4,4′-bipyridine were synthesized and characterized by IR spectroscopy and X-ray diffraction. The complex [Mn(HEt2mal)2(bpy)(H2O)2]n (1) (H2Et2mal is diethylmalonic acid, bpy is 4,4′-bipyridine) contains six-coordinate metal atoms and has a chain structure. In the structure of complex 1, two interpenetrating frameworks are formed through hydrogen bonds. The coordination polymer {[Cu2(Et2mal)2(bpy)(H2O)]•6 H2O}n (2) contains four- and five-coordinate copper(ii) cations and forms infinite layers perpendicular to the crystallographic axis a.
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Chistyakov A. S. et al. Synthesis and structure of copper(ii) and manganese(ii) diethylmalonates with 4,4′-bipyridine // Russian Chemical Bulletin. 2024. Vol. 73. No. 10. pp. 2838-2843.
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Chistyakov A. S., Knyazev D. A., Zorina-Tikhonova E. N., Kiskin M. A., Vologzhanina A. V., Eremenko I. L. Synthesis and structure of copper(ii) and manganese(ii) diethylmalonates with 4,4′-bipyridine // Russian Chemical Bulletin. 2024. Vol. 73. No. 10. pp. 2838-2843.
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TY - JOUR
DO - 10.1007/s11172-024-4400-x
UR - https://link.springer.com/10.1007/s11172-024-4400-x
TI - Synthesis and structure of copper(ii) and manganese(ii) diethylmalonates with 4,4′-bipyridine
T2 - Russian Chemical Bulletin
AU - Chistyakov, A. S.
AU - Knyazev, D. A.
AU - Zorina-Tikhonova, E. N.
AU - Kiskin, M. A.
AU - Vologzhanina, A. V.
AU - Eremenko, I. L.
PY - 2024
DA - 2024/10/01
PB - Springer Nature
SP - 2838-2843
IS - 10
VL - 73
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2024_Chistyakov,
author = {A. S. Chistyakov and D. A. Knyazev and E. N. Zorina-Tikhonova and M. A. Kiskin and A. V. Vologzhanina and I. L. Eremenko},
title = {Synthesis and structure of copper(ii) and manganese(ii) diethylmalonates with 4,4′-bipyridine},
journal = {Russian Chemical Bulletin},
year = {2024},
volume = {73},
publisher = {Springer Nature},
month = {oct},
url = {https://link.springer.com/10.1007/s11172-024-4400-x},
number = {10},
pages = {2838--2843},
doi = {10.1007/s11172-024-4400-x}
}
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Chistyakov, A. S., et al. “Synthesis and structure of copper(ii) and manganese(ii) diethylmalonates with 4,4′-bipyridine.” Russian Chemical Bulletin, vol. 73, no. 10, Oct. 2024, pp. 2838-2843. https://link.springer.com/10.1007/s11172-024-4400-x.