Photoinduced radical sulfur dioxide insertion with asymmetric cyclization of alkenes: accessing β-chiral sulfones bearing S-stereocentric cyclic sulfinamides
Publication type: Journal Article
Publication date: 2024-09-26
scimago Q1
wos Q1
SJR: 2.377
CiteScore: 13.8
Impact factor: 9.7
ISSN: 16747291, 18691870
Abstract
The generation of various β-chiral sulfones bearing chiral cyclic sulfinamides through photoredox-catalyzed sulfur dioxide insertion with asymmetric radical cyclization is described. This method features a broad substrate scope and excellent stereo-specificity. Computational studies reveal that the dispersion interaction between sulfinyl group and CH2SO2Ph group plays a crucial role in the stereoselectivity control.
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7
Total citations:
7
Citations from 2024:
7
(100%)
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Huang J. et al. Photoinduced radical sulfur dioxide insertion with asymmetric cyclization of alkenes: accessing β-chiral sulfones bearing S-stereocentric cyclic sulfinamides // Science China Chemistry. 2024.
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Huang J., Wang C., Wang X., Zhou X., Xiao W., Wu J. Photoinduced radical sulfur dioxide insertion with asymmetric cyclization of alkenes: accessing β-chiral sulfones bearing S-stereocentric cyclic sulfinamides // Science China Chemistry. 2024.
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TY - JOUR
DO - 10.1007/s11426-024-2151-x
UR - https://link.springer.com/10.1007/s11426-024-2151-x
TI - Photoinduced radical sulfur dioxide insertion with asymmetric cyclization of alkenes: accessing β-chiral sulfones bearing S-stereocentric cyclic sulfinamides
T2 - Science China Chemistry
AU - Huang, Jiapian
AU - Wang, Chenxin
AU - Wang, Xu
AU - Zhou, Xiaoyu
AU - Xiao, Wei
AU - Wu, Jie
PY - 2024
DA - 2024/09/26
PB - Springer Nature
SN - 1674-7291
SN - 1869-1870
ER -
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@article{2024_Huang,
author = {Jiapian Huang and Chenxin Wang and Xu Wang and Xiaoyu Zhou and Wei Xiao and Jie Wu},
title = {Photoinduced radical sulfur dioxide insertion with asymmetric cyclization of alkenes: accessing β-chiral sulfones bearing S-stereocentric cyclic sulfinamides},
journal = {Science China Chemistry},
year = {2024},
publisher = {Springer Nature},
month = {sep},
url = {https://link.springer.com/10.1007/s11426-024-2151-x},
doi = {10.1007/s11426-024-2151-x}
}