Photochemical and Photobiological Sciences, volume 22, issue 11, pages 2651-2673
Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence
Pugachev A. D.
1
,
Makarova Nadezhda I
1
,
Rostovtseva Irina A
1
,
Ozhogin Ilya V
1
,
Dmitriev Vitaly S.
1
,
Borodkin Gennady S
1
,
Tkachev Valery V.
2
,
Utenyshev Andrey N.
2
,
Sazykina Marina A
3
,
Sazykin Ivan S
3
,
Azhogina Tatiana N.
3
,
Karchava Shorena K.
3
,
Klimova Maria V.
3
,
Metelitsa Anatoly V
1
,
Lukyanov Boris S
1
Publication type: Journal Article
Publication date: 2023-09-21
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.1
ISSN: 1474905X, 14749092
Physical and Theoretical Chemistry
Abstract
This study focuses on the molecular design and synthesis of salt spiropyrans with near-IR fluorescence. The structure of the obtained compounds was confirmed by NMR, IR and mass spectroscopy. In the course of studying the spectral and photoluminescent characteristics, it was possible to reveal the effect of some substituents in various positions on the properties of spiropyran dyes. Due to the structural similarity of one of the isomers to cyanine dyes, the obtained compounds are of interest as potential fluorescent probes for bioimagimg, in particular, for DNA studies. To reveal their ability of binding to DNA molecules molecular docking was carried out. Toxic effects of compounds demonstrating NIR fluorescence were studied on biofilms, as well as using bacterial lux-biosensors.
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Pugachev A. D. et al. Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence // Photochemical and Photobiological Sciences. 2023. Vol. 22. No. 11. pp. 2651-2673.
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Pugachev A. D., Kozlenko A. S., Makarova N. I., Rostovtseva I. A., Ozhogin I. V., Dmitriev V. S., Borodkin G. S., Tkachev V. V., Utenyshev A. N., Sazykina M. A., Sazykin I. S., Azhogina T. N., Karchava S. K., Klimova M. V., Metelitsa A. V., Lukyanov B. S. Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence // Photochemical and Photobiological Sciences. 2023. Vol. 22. No. 11. pp. 2651-2673.
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TY - JOUR
DO - 10.1007/s43630-023-00479-1
UR - https://doi.org/10.1007%2Fs43630-023-00479-1
TI - Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence
T2 - Photochemical and Photobiological Sciences
AU - Pugachev, A. D.
AU - Kozlenko, Anastasia S
AU - Makarova, Nadezhda I
AU - Rostovtseva, Irina A
AU - Ozhogin, Ilya V
AU - Dmitriev, Vitaly S.
AU - Borodkin, Gennady S
AU - Tkachev, Valery V.
AU - Utenyshev, Andrey N.
AU - Sazykina, Marina A
AU - Sazykin, Ivan S
AU - Azhogina, Tatiana N.
AU - Karchava, Shorena K.
AU - Klimova, Maria V.
AU - Metelitsa, Anatoly V
AU - Lukyanov, Boris S
PY - 2023
DA - 2023/09/21 00:00:00
PB - Springer Nature
SP - 2651-2673
IS - 11
VL - 22
SN - 1474-905X
SN - 1474-9092
ER -
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@article{2023_Pugachev,
author = {A. D. Pugachev and Anastasia S Kozlenko and Nadezhda I Makarova and Irina A Rostovtseva and Ilya V Ozhogin and Vitaly S. Dmitriev and Gennady S Borodkin and Valery V. Tkachev and Andrey N. Utenyshev and Marina A Sazykina and Ivan S Sazykin and Tatiana N. Azhogina and Shorena K. Karchava and Maria V. Klimova and Anatoly V Metelitsa and Boris S Lukyanov},
title = {Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence},
journal = {Photochemical and Photobiological Sciences},
year = {2023},
volume = {22},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007%2Fs43630-023-00479-1},
number = {11},
pages = {2651--2673},
doi = {10.1007/s43630-023-00479-1}
}
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Pugachev, A. D., et al. “Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence.” Photochemical and Photobiological Sciences, vol. 22, no. 11, Sep. 2023, pp. 2651-2673. https://doi.org/10.1007%2Fs43630-023-00479-1.