Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence
A. D. Pugachev
1
,
Nadezhda I Makarova
1
,
Irina A Rostovtseva
1
,
Ilya V Ozhogin
1
,
Gennady S Borodkin
1
,
Valery V. Tkachev
2
,
Andrey N. Utenyshev
2
,
Marina A Sazykina
3
,
Ivan S Sazykin
3
,
Tatiana N. Azhogina
3
,
Shorena K. Karchava
3
,
Maria V. Klimova
3
,
Anatoly V Metelitsa
1
,
Boris S Lukyanov
1
Publication type: Journal Article
Publication date: 2023-09-21
scimago Q2
wos Q2
SJR: 0.629
CiteScore: 5.1
Impact factor: 3.2
ISSN: 1474905X, 14749092
PubMed ID:
37733213
Physical and Theoretical Chemistry
Abstract
This study focuses on the molecular design and synthesis of salt spiropyrans with near-IR fluorescence. The structure of the obtained compounds was confirmed by NMR, IR and mass spectroscopy. In the course of studying the spectral and photoluminescent characteristics, it was possible to reveal the effect of some substituents in various positions on the properties of spiropyran dyes. Due to the structural similarity of one of the isomers to cyanine dyes, the obtained compounds are of interest as potential fluorescent probes for bioimagimg, in particular, for DNA studies. To reveal their ability of binding to DNA molecules molecular docking was carried out. Toxic effects of compounds demonstrating NIR fluorescence were studied on biofilms, as well as using bacterial lux-biosensors.
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Citations from 2024:
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Pugachev A. D. et al. Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence // Photochemical and Photobiological Sciences. 2023. Vol. 22. No. 11. pp. 2651-2673.
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Pugachev A. D., Kozlenko A. S., Makarova N. I., Rostovtseva I. A., Ozhogin I. V., Dmitriev V. S., Borodkin G. S., Tkachev V. V., Utenyshev A. N., Sazykina M. A., Sazykin I. S., Azhogina T. N., Karchava S. K., Klimova M. V., Metelitsa A. V., Lukyanov B. S. Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence // Photochemical and Photobiological Sciences. 2023. Vol. 22. No. 11. pp. 2651-2673.
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TY - JOUR
DO - 10.1007/s43630-023-00479-1
UR - https://doi.org/10.1007/s43630-023-00479-1
TI - Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence
T2 - Photochemical and Photobiological Sciences
AU - Pugachev, A. D.
AU - Kozlenko, Anastasia S
AU - Makarova, Nadezhda I
AU - Rostovtseva, Irina A
AU - Ozhogin, Ilya V
AU - Dmitriev, Vitaly S.
AU - Borodkin, Gennady S
AU - Tkachev, Valery V.
AU - Utenyshev, Andrey N.
AU - Sazykina, Marina A
AU - Sazykin, Ivan S
AU - Azhogina, Tatiana N.
AU - Karchava, Shorena K.
AU - Klimova, Maria V.
AU - Metelitsa, Anatoly V
AU - Lukyanov, Boris S
PY - 2023
DA - 2023/09/21
PB - Springer Nature
SP - 2651-2673
IS - 11
VL - 22
PMID - 37733213
SN - 1474-905X
SN - 1474-9092
ER -
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@article{2023_Pugachev,
author = {A. D. Pugachev and Anastasia S Kozlenko and Nadezhda I Makarova and Irina A Rostovtseva and Ilya V Ozhogin and Vitaly S. Dmitriev and Gennady S Borodkin and Valery V. Tkachev and Andrey N. Utenyshev and Marina A Sazykina and Ivan S Sazykin and Tatiana N. Azhogina and Shorena K. Karchava and Maria V. Klimova and Anatoly V Metelitsa and Boris S Lukyanov},
title = {Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence},
journal = {Photochemical and Photobiological Sciences},
year = {2023},
volume = {22},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s43630-023-00479-1},
number = {11},
pages = {2651--2673},
doi = {10.1007/s43630-023-00479-1}
}
Cite this
MLA
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Pugachev, A. D., et al. “Molecular design and synthesis of methoxy-substitued spiropyrans with photomodulated NIR-fluorescence.” Photochemical and Photobiological Sciences, vol. 22, no. 11, Sep. 2023, pp. 2651-2673. https://doi.org/10.1007/s43630-023-00479-1.