Role of steric factors in formation of O?H...M hydrogen bonds with metallocenes
Publication type: Journal Article
Publication date: 1995-10-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Molecular mechanics calculations of geometric parameters and energies of molecular complexes with a O-H...M hydrogen bond have been performed for osmocene and decamethylosmocene with three proton donors. The results of calculations demonstrated that when rings are methylated, steric hindrances to formation of this hydrogen bond increase. This is the reason for anomalously low formation constants of H-bonded Cp 2 * M molecular associates compared to CP2M associates.
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Timofeeva T. V. et al. Role of steric factors in formation of O?H...M hydrogen bonds with metallocenes // Russian Chemical Bulletin. 1995. Vol. 44. No. 10. pp. 1845-1847.
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Timofeeva T. V., Shubina E. S., Krylov A., Epshtein L. M. Role of steric factors in formation of O?H...M hydrogen bonds with metallocenes // Russian Chemical Bulletin. 1995. Vol. 44. No. 10. pp. 1845-1847.
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TY - JOUR
DO - 10.1007/BF00707208
UR - https://doi.org/10.1007/BF00707208
TI - Role of steric factors in formation of O?H...M hydrogen bonds with metallocenes
T2 - Russian Chemical Bulletin
AU - Timofeeva, T V
AU - Shubina, E. S.
AU - Krylov, A.N.
AU - Epshtein, L M
PY - 1995
DA - 1995/10/01
PB - Springer Nature
SP - 1845-1847
IS - 10
VL - 44
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{1995_Timofeeva,
author = {T V Timofeeva and E. S. Shubina and A.N. Krylov and L M Epshtein},
title = {Role of steric factors in formation of O?H...M hydrogen bonds with metallocenes},
journal = {Russian Chemical Bulletin},
year = {1995},
volume = {44},
publisher = {Springer Nature},
month = {oct},
url = {https://doi.org/10.1007/BF00707208},
number = {10},
pages = {1845--1847},
doi = {10.1007/BF00707208}
}
Cite this
MLA
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Timofeeva, T. V., et al. “Role of steric factors in formation of O?H...M hydrogen bonds with metallocenes.” Russian Chemical Bulletin, vol. 44, no. 10, Oct. 1995, pp. 1845-1847. https://doi.org/10.1007/BF00707208.
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