Springer Nature
Russian Chemical Bulletin
,  volume 40 ,  issue 12 ,  pages 2496-2505

The role of pH in the synthesis of diaziridines

Publication type: Journal Article
Publication date: 1991-12-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The greatest yield in the synthesis of diaziridines from carbonyl compounds, amines, and aminating reagents in water is achieved at a specific pH, which shifts to less alkaline values with increasing -I effect of the substituents in the carbonyl compound and with decreasing pKBH+ value of the amine. The role of pH is related to the conditions for the generation of an immonium from the intermediateα-aminocarbinol. The nuclear Overhauser effect was used to determine the orientation of the substituents in several diastereomers of the didikyldiaziridines obtained.
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GOST |
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GOST Copy
Kuznetsov V. V. et al. The role of pH in the synthesis of diaziridines // Russian Chemical Bulletin. 1991. Vol. 40. No. 12. pp. 2496-2505.
GOST all authors (up to 50) Copy
Kuznetsov V. V., Makhova N. N., Strelenko Y., Khmelnitskii L. I. The role of pH in the synthesis of diaziridines // Russian Chemical Bulletin. 1991. Vol. 40. No. 12. pp. 2496-2505.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1007/BF00959732
UR - https://doi.org/10.1007/BF00959732
TI - The role of pH in the synthesis of diaziridines
T2 - Russian Chemical Bulletin
AU - Kuznetsov, V. V.
AU - Makhova, N N
AU - Strelenko, Yu.A.
AU - Khmelnitskii, L. I.
PY - 1991
DA - 1991/12/01
PB - Springer Nature
SP - 2496-2505
IS - 12
VL - 40
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1991_Kuznetsov,
author = {V. V. Kuznetsov and N N Makhova and Yu.A. Strelenko and L. I. Khmelnitskii},
title = {The role of pH in the synthesis of diaziridines},
journal = {Russian Chemical Bulletin},
year = {1991},
volume = {40},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/BF00959732},
number = {12},
pages = {2496--2505},
doi = {10.1007/BF00959732}
}
MLA
Cite this
MLA Copy
Kuznetsov, V. V., et al. “The role of pH in the synthesis of diaziridines.” Russian Chemical Bulletin, vol. 40, no. 12, Dec. 1991, pp. 2496-2505. https://doi.org/10.1007/BF00959732.