Magnetic properties of binuclear high-spin trimethylacetate nickel(II) complexes
Publication type: Journal Article
Publication date: 2000-03-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The static magnetic susceptibility of mononuclear trimethylacetate nickel complex Ni(NH2Ph)4(OOCCMe3)2 (3) and binuclear complexes Ni2(μ-OH2)(μ-OOCCMe3)2(OOCCMe3)2(dipy)2 (4) and Ni2(μ-OOCCMe3)4py2 (5) was measured in the temperature range of 2–300 K. The magnetic behavior of3 is typical of mononuclear complexes with the Ni11 atom in the octahedral environment. Numerical calculations of the temperature dependence of magnetic susceptibility with inclusion of isotropic exchange interactions (J) and single-ion initial splitting parameters showed that the magnetic behavior of complexes4 and 5 can be interpreted in terms of ferromagnetic (for4) and antiferromagnetic (for5) interactions.
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Novotortsev V. M. et al. Magnetic properties of binuclear high-spin trimethylacetate nickel(II) complexes // Russian Chemical Bulletin. 2000. Vol. 49. No. 3. pp. 438-443.
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Novotortsev V. M., Rakitin Y., Nefedov S., Eremenko I. L. Magnetic properties of binuclear high-spin trimethylacetate nickel(II) complexes // Russian Chemical Bulletin. 2000. Vol. 49. No. 3. pp. 438-443.
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RIS
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TY - JOUR
DO - 10.1007/BF02494772
UR - https://doi.org/10.1007/BF02494772
TI - Magnetic properties of binuclear high-spin trimethylacetate nickel(II) complexes
T2 - Russian Chemical Bulletin
AU - Novotortsev, V. M.
AU - Rakitin, Yu.V.
AU - Nefedov, S.E.
AU - Eremenko, I. L.
PY - 2000
DA - 2000/03/01
PB - Springer Nature
SP - 438-443
IS - 3
VL - 49
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2000_Novotortsev,
author = {V. M. Novotortsev and Yu.V. Rakitin and S.E. Nefedov and I. L. Eremenko},
title = {Magnetic properties of binuclear high-spin trimethylacetate nickel(II) complexes},
journal = {Russian Chemical Bulletin},
year = {2000},
volume = {49},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/BF02494772},
number = {3},
pages = {438--443},
doi = {10.1007/BF02494772}
}
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MLA
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Novotortsev, V. M., et al. “Magnetic properties of binuclear high-spin trimethylacetate nickel(II) complexes.” Russian Chemical Bulletin, vol. 49, no. 3, Mar. 2000, pp. 438-443. https://doi.org/10.1007/BF02494772.
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