New polynuclear cobalt trimethylacetate complexes: synthesis and structure
M A Golubnichaya
1
,
A. A. Sidorov
1
,
I.G. Fomina
1
,
M O Ponina
1
,
S M Deomidov
1
,
S.E. Nefedov
1
,
I L Ermenko
1
,
I. I. Moiseev
1
Publication type: Journal Article
Publication date: 1999-09-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Extraction of polymer (1), formed in the reaction of CoCl2 with KOOCBut, with boiling hexane gives crystals of hexamer Co6(μ3-OH)2(OOCBu1)10(HOOCBu1)4 (2). According to data of X-ray study, four Co11 atoms in the hexanuclear molecule2 have an octahedral ligand environment and two Co11 atoms have a tetrahedral one. Dissolution of polymer1 in EtOH results in its splitting into Co4(μ3-OH)2(OOCBu1)6(HOEt)6 tetramers (3). In molecule3, two asymmetric dimeric (η2-OOCBut)(EtOH)Co(μ-OOCBut)Co(HOEt)2 fragments are bound by two tridentate bridging OH groups.
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Total citations:
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Citations from 2024:
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(12%)
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GOST
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Golubnichaya M. A. et al. New polynuclear cobalt trimethylacetate complexes: synthesis and structure // Russian Chemical Bulletin. 1999. Vol. 48. No. 9. pp. 1751-1756.
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Golubnichaya M. A., Sidorov A. A., Fomina I., Ponina M. O., Deomidov S. M., Nefedov S., Ermenko I. L., Moiseev I. I. New polynuclear cobalt trimethylacetate complexes: synthesis and structure // Russian Chemical Bulletin. 1999. Vol. 48. No. 9. pp. 1751-1756.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/BF02494824
UR - https://doi.org/10.1007/BF02494824
TI - New polynuclear cobalt trimethylacetate complexes: synthesis and structure
T2 - Russian Chemical Bulletin
AU - Golubnichaya, M A
AU - Sidorov, A. A.
AU - Fomina, I.G.
AU - Ponina, M O
AU - Deomidov, S M
AU - Nefedov, S.E.
AU - Ermenko, I L
AU - Moiseev, I. I.
PY - 1999
DA - 1999/09/01
PB - Springer Nature
SP - 1751-1756
IS - 9
VL - 48
SN - 1066-5285
SN - 1573-9171
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1999_Golubnichaya,
author = {M A Golubnichaya and A. A. Sidorov and I.G. Fomina and M O Ponina and S M Deomidov and S.E. Nefedov and I L Ermenko and I. I. Moiseev},
title = {New polynuclear cobalt trimethylacetate complexes: synthesis and structure},
journal = {Russian Chemical Bulletin},
year = {1999},
volume = {48},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/BF02494824},
number = {9},
pages = {1751--1756},
doi = {10.1007/BF02494824}
}
Cite this
MLA
Copy
Golubnichaya, M. A., et al. “New polynuclear cobalt trimethylacetate complexes: synthesis and structure.” Russian Chemical Bulletin, vol. 48, no. 9, Sep. 1999, pp. 1751-1756. https://doi.org/10.1007/BF02494824.