Synthesis, structures, and magnetic properties of binuclear carboxylate complexes with NiII and NiIII atoms
I. L. Eremenko
1
,
M A Golubnichaya
1
,
S.E. Nefedov
1
,
A. A. Sidorov
1
,
I F Golovaneva
1
,
V.I. Burkov
2
,
O.G Ellert
1
,
V. M. Novotortsev
1
,
L T Ermenko
3
,
A. Sousa
4
,
M.R. Bermejo
4
Publication type: Journal Article
Publication date: 1998-04-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reaction of NiCl2·6H2O with Me3CCOOH and KOH taken in a molar ratio of 1:2:2 in water afforded the nonanuclear antiferromagnetic complex Py2Ni2(Me3CCOOH)2(OOCCMe3)2(μ-OOCCMe3)2(μ-OH2), which apparently contains NiII and NiIII atoms. The complex was isolated by extraction with CH2Cl2, benzene, or hexane. The reactions of this complex with pyridine bases (pyridine (Py), 3,4-lutidine (Lut), and nicorandil (Nic)) gave the adducts L4Ni2(OOCCMe3)2(μ-OOCCMe3)2(μ-OH) (L=Py, Lut, or Nic, respectively). According to magnetic measurements, intramolecular ferromagnetic exchange interactions in these adducts are complemented by intermolecular antiferromagnetic interactions. Pyrolysis of the pyridine adduct in air or under an inert atmosphere in xylene yielded the antiferromagnetic complex Py2Ni2(Me3CCOOH)2(OOCCMe3)2(μ-OOCCMe3)2(μ-OH2), which contains NiII atoms. The structures of all the complexes synthesized were established by X-ray diffraction analysis. The electronic absorption spectra of these compounds are considered.
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Eremenko I. L. et al. Synthesis, structures, and magnetic properties of binuclear carboxylate complexes with NiII and NiIII atoms // Russian Chemical Bulletin. 1998. Vol. 47. No. 4. pp. 704-718.
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Eremenko I. L., Golubnichaya M. A., Nefedov S., Sidorov A. A., Golovaneva I. F., Burkov V., Ellert O., Novotortsev V. M., Ermenko L. T., Sousa A., Bermejo M. Synthesis, structures, and magnetic properties of binuclear carboxylate complexes with NiII and NiIII atoms // Russian Chemical Bulletin. 1998. Vol. 47. No. 4. pp. 704-718.
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RIS
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TY - JOUR
DO - 10.1007/BF02495984
UR - https://doi.org/10.1007/BF02495984
TI - Synthesis, structures, and magnetic properties of binuclear carboxylate complexes with NiII and NiIII atoms
T2 - Russian Chemical Bulletin
AU - Eremenko, I. L.
AU - Golubnichaya, M A
AU - Nefedov, S.E.
AU - Sidorov, A. A.
AU - Golovaneva, I F
AU - Burkov, V.I.
AU - Ellert, O.G
AU - Novotortsev, V. M.
AU - Ermenko, L T
AU - Sousa, A.
AU - Bermejo, M.R.
PY - 1998
DA - 1998/04/01
PB - Springer Nature
SP - 704-718
IS - 4
VL - 47
SN - 1066-5285
SN - 1573-9171
ER -
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@article{1998_Eremenko,
author = {I. L. Eremenko and M A Golubnichaya and S.E. Nefedov and A. A. Sidorov and I F Golovaneva and V.I. Burkov and O.G Ellert and V. M. Novotortsev and L T Ermenko and A. Sousa and M.R. Bermejo},
title = {Synthesis, structures, and magnetic properties of binuclear carboxylate complexes with NiII and NiIII atoms},
journal = {Russian Chemical Bulletin},
year = {1998},
volume = {47},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/BF02495984},
number = {4},
pages = {704--718},
doi = {10.1007/BF02495984}
}
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MLA
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Eremenko, I. L., et al. “Synthesis, structures, and magnetic properties of binuclear carboxylate complexes with NiII and NiIII atoms.” Russian Chemical Bulletin, vol. 47, no. 4, Apr. 1998, pp. 704-718. https://doi.org/10.1007/BF02495984.
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