Problems of unusual hydrogen bonds between proton donors and transition metal hydrides and borohydrides
E. S. Shubina
1
,
N. V. Belkova
1
,
E.V Bakhmutova
1
,
L N Saitkulova
1
,
A V Ionidis
1
,
L M Epstein
1
Publication type: Journal Article
Publication date: 1998-05-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The results of experimental and theoretical studies of intermolecular MH...HX and BH...HX hydrogen bonds with the hydride hydrogen atom acting as a proton accepting site are analyzed. Spectral (IR and NMR) criteria for their formation are presented. The spectral, structural, and thermodynamic characteristics of these unusual hydrogen bonds obey the regularities found for classical hydrogen bonds. It was shown that the MH...HX bonds participate in the proton transfer with the formation of nonclassical cationic hydrides and the |M(η2-H2|+ hydrogen bonds are formed in low-polarity media. Problems arising in this new line of investigations are discussed.
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GOST
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Shubina E. S. et al. Problems of unusual hydrogen bonds between proton donors and transition metal hydrides and borohydrides // Russian Chemical Bulletin. 1998. Vol. 47. No. 5. pp. 817-822.
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Shubina E. S., Belkova N. V., Bakhmutova E., Saitkulova L. N., Ionidis A. V., Epstein L. M. Problems of unusual hydrogen bonds between proton donors and transition metal hydrides and borohydrides // Russian Chemical Bulletin. 1998. Vol. 47. No. 5. pp. 817-822.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/BF02498147
UR - https://doi.org/10.1007/BF02498147
TI - Problems of unusual hydrogen bonds between proton donors and transition metal hydrides and borohydrides
T2 - Russian Chemical Bulletin
AU - Shubina, E. S.
AU - Belkova, N. V.
AU - Bakhmutova, E.V
AU - Saitkulova, L N
AU - Ionidis, A V
AU - Epstein, L M
PY - 1998
DA - 1998/05/01
PB - Springer Nature
SP - 817-822
IS - 5
VL - 47
SN - 1066-5285
SN - 1573-9171
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1998_Shubina,
author = {E. S. Shubina and N. V. Belkova and E.V Bakhmutova and L N Saitkulova and A V Ionidis and L M Epstein},
title = {Problems of unusual hydrogen bonds between proton donors and transition metal hydrides and borohydrides},
journal = {Russian Chemical Bulletin},
year = {1998},
volume = {47},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1007/BF02498147},
number = {5},
pages = {817--822},
doi = {10.1007/BF02498147}
}
Cite this
MLA
Copy
Shubina, E. S., et al. “Problems of unusual hydrogen bonds between proton donors and transition metal hydrides and borohydrides.” Russian Chemical Bulletin, vol. 47, no. 5, May. 1998, pp. 817-822. https://doi.org/10.1007/BF02498147.
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