Kinetics and Catalysis

, volume 41 , issue 3 , pages 399-401

Radical-chain reactions of CCl4 with hydrocarbons in the presence of silica-immobilized copper-containing catalysts

V. V. Smirnov ¹

E. N. Golubeva ¹

O A Zagorskaya ¹

S M Nevskaya ¹

M M Levitskii ²

V Yu Zufman ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Chemistry, Moscow State University, Moscow, Russia |

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia |

Publication type: Journal Article

Publication date: 2000-05-01

Pleiades Publishing

Kinetics and Catalysis

scimago Q3

wos Q4

SJR: 0.260

CiteScore: 1.9

Impact factor: 1.4

ISSN: 00231584, 16083210

DOI: 10.1007/BF02755379

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General Chemistry

Catalysis

Computer Science Applications

Modeling and Simulation

Abstract

The activities of two catalytic systems toward the exchange reaction of CCl4 with hydrocarbons are compared: a copper chloride complex with DMF and polycopperphenylsiloxane (PCPS). PCPS is a very stable catalyst. It completely preserves its catalytic activity after six catalytic cycles. Competitive reactions with the pairs of hydrocarbons suggested a radical-chain mechanism for the title reaction for both catalysts.

Found

2 citations

Bilyachenko Alexey

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DSc in Chemistry

87 publications, 2 002 citations, 13 reviews

h-index: 28

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Peoples' Friendship University of Russia

1 citation

Shubina Elena

DSc in Chemistry, professor

263 publications, 5 798 citations, 16 reviews

h-index: 37

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Molecular spectroscopy

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Smirnov V. V. et al. Radical-chain reactions of CCl4 with hydrocarbons in the presence of silica-immobilized copper-containing catalysts // Kinetics and Catalysis. 2000. Vol. 41. No. 3. pp. 399-401.

GOST all authors (up to 50) Copy

Smirnov V. V., Golubeva E. N., Zagorskaya O. A., Nevskaya S. M., Levitskii M. M., Zufman V. Yu. Radical-chain reactions of CCl4 with hydrocarbons in the presence of silica-immobilized copper-containing catalysts // Kinetics and Catalysis. 2000. Vol. 41. No. 3. pp. 399-401.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1007/BF02755379

UR - https://doi.org/10.1007/BF02755379

TI - Radical-chain reactions of CCl4 with hydrocarbons in the presence of silica-immobilized copper-containing catalysts

T2 - Kinetics and Catalysis

AU - Smirnov, V. V.

AU - Golubeva, E. N.

AU - Zagorskaya, O A

AU - Nevskaya, S M

AU - Levitskii, M M

AU - Zufman, V Yu

PY - 2000

DA - 2000/05/01

PB - Pleiades Publishing

SP - 399-401

IS - 3

VL - 41

SN - 0023-1584

SN - 1608-3210

ER -

BibTex |

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@article{2000_Smirnov,

author = {V. V. Smirnov and E. N. Golubeva and O A Zagorskaya and S M Nevskaya and M M Levitskii and V Yu Zufman},

title = {Radical-chain reactions of CCl4 with hydrocarbons in the presence of silica-immobilized copper-containing catalysts},

journal = {Kinetics and Catalysis},

year = {2000},

volume = {41},

publisher = {Pleiades Publishing},

month = {may},

url = {https://doi.org/10.1007/BF02755379},

number = {3},

pages = {399--401},

doi = {10.1007/BF02755379}

}

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Smirnov, V. V., et al. “Radical-chain reactions of CCl4 with hydrocarbons in the presence of silica-immobilized copper-containing catalysts.” Kinetics and Catalysis, vol. 41, no. 3, May. 2000, pp. 399-401. https://doi.org/10.1007/BF02755379.