Photo-optical properties of photopolymerizable cholesteric compositions
Publication type: Journal Article
Publication date: 2007-01-19
scimago Q2
wos Q3
SJR: 0.431
CiteScore: 4.5
Impact factor: 2.3
ISSN: 0303402X, 14351536
Materials Chemistry
Physical and Theoretical Chemistry
Colloid and Surface Chemistry
Polymers and Plastics
Abstract
Compositions consisting of nematogenic diacrylate monomer and chiral dopants capable of forming the cholesteric mesophase and of photopolymerizing were obtained and studied. For the first time, the change of optical properties and cholesteric helix pitch during photocrosslinking of diacrylate under UV irradiation (365 nm) was investigated. The kinetics of photopolymerization was studied and several stages of this process were observed. Cholesteric photopolymerizable blends containing chiral photosensitive dopant capable of E–Z isomerizing under UV irradiation (313 nm) were studied. The decrease of the helix twisting power of the dopant during photoisomerization was observed resulting in untwisting of the helix and shift of the selective light reflection peak into the long-wavelength region of the spectrum. The possibility of the photoregulation of optical properties of such blends with following fixation of structure and of these properties by means of photopolymerization under UV irradiation (365 nm) was demonstrated.
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12
Total citations:
12
Citations from 2024:
8
(66%)
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MLA
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GOST
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Dadivanyan N. et al. Photo-optical properties of photopolymerizable cholesteric compositions // Colloid and Polymer Science. 2007. Vol. 285. No. 6. pp. 681-686.
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Dadivanyan N., Bobrovsky A., Shibaev V. Photo-optical properties of photopolymerizable cholesteric compositions // Colloid and Polymer Science. 2007. Vol. 285. No. 6. pp. 681-686.
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RIS
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TY - JOUR
DO - 10.1007/s00396-006-1593-5
UR - http://link.springer.com/10.1007/s00396-006-1593-5
TI - Photo-optical properties of photopolymerizable cholesteric compositions
T2 - Colloid and Polymer Science
AU - Dadivanyan, Natalia
AU - Bobrovsky, Alexey
AU - Shibaev, Valery
PY - 2007
DA - 2007/01/19
PB - Springer Nature
SP - 681-686
IS - 6
VL - 285
SN - 0303-402X
SN - 1435-1536
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2007_Dadivanyan,
author = {Natalia Dadivanyan and Alexey Bobrovsky and Valery Shibaev},
title = {Photo-optical properties of photopolymerizable cholesteric compositions},
journal = {Colloid and Polymer Science},
year = {2007},
volume = {285},
publisher = {Springer Nature},
month = {jan},
url = {http://link.springer.com/10.1007/s00396-006-1593-5},
number = {6},
pages = {681--686},
doi = {10.1007/s00396-006-1593-5}
}
Cite this
MLA
Copy
Dadivanyan, Natalia, et al. “Photo-optical properties of photopolymerizable cholesteric compositions.” Colloid and Polymer Science, vol. 285, no. 6, Jan. 2007, pp. 681-686. http://link.springer.com/10.1007/s00396-006-1593-5.
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