Synthesis and Characterization of N 3 -(2,2,2-Trinitroethyl)-1,2,4-Oxadiazole-3,5-Diamine
Тип публикации: Journal Article
Дата публикации: 2017-06-01
SCImago Q3
WOS Q4
БС3
SJR: 0.281
CiteScore: 2.7
Impact factor: 1
ISSN: 00093122, 15738353
Organic Chemistry
Краткое описание
The reaction of 1,2,4-oxadiazole-3,5-diamine with 2-fluoro-2,2-dinitroethanol or 2,2,2-trinitroethanol was studied. Only the 3-amino group was found to be reactive and underwent efficient Mannich-type condensation with 2,2,2-trinitroethanol, while only trace amounts of product from condensation with 2-fluoro-2,2-dinitroethanol were formed. N 3 -(2,2,2-Trinitroethyl)-1,2,4-oxadiazole-3,5-diamine was fully characterized, and its crystal structure and explosive sensitivity properties were determined. Calculated performance properties show that the product is a promising RDX-like material with a higher oxidizing potential.
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Chavez D. E., Schulze M. C., Parrish D. A. Synthesis and Characterization of N 3 -(2,2,2-Trinitroethyl)-1,2,4-Oxadiazole-3,5-Diamine // Chemistry of Heterocyclic Compounds. 2017. Vol. 53. No. 6-7. pp. 737-739.
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Chavez D. E., Schulze M. C., Parrish D. A. Synthesis and Characterization of N 3 -(2,2,2-Trinitroethyl)-1,2,4-Oxadiazole-3,5-Diamine // Chemistry of Heterocyclic Compounds. 2017. Vol. 53. No. 6-7. pp. 737-739.
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TY - JOUR
DO - 10.1007/s10593-017-2119-4
UR - https://doi.org/10.1007/s10593-017-2119-4
TI - Synthesis and Characterization of N 3 -(2,2,2-Trinitroethyl)-1,2,4-Oxadiazole-3,5-Diamine
T2 - Chemistry of Heterocyclic Compounds
AU - Chavez, David E.
AU - Schulze, Maxwell C.
AU - Parrish, Damon A.
PY - 2017
DA - 2017/06/01
PB - Springer Nature
SP - 737-739
IS - 6-7
VL - 53
SN - 0009-3122
SN - 1573-8353
ER -
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@article{2017_Chavez,
author = {David E. Chavez and Maxwell C. Schulze and Damon A. Parrish},
title = {Synthesis and Characterization of N 3 -(2,2,2-Trinitroethyl)-1,2,4-Oxadiazole-3,5-Diamine},
journal = {Chemistry of Heterocyclic Compounds},
year = {2017},
volume = {53},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s10593-017-2119-4},
number = {6-7},
pages = {737--739},
doi = {10.1007/s10593-017-2119-4}
}
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Chavez, David E., et al. “Synthesis and Characterization of N 3 -(2,2,2-Trinitroethyl)-1,2,4-Oxadiazole-3,5-Diamine.” Chemistry of Heterocyclic Compounds, vol. 53, no. 6-7, Jun. 2017, pp. 737-739. https://doi.org/10.1007/s10593-017-2119-4.
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