Chemistry of Heterocyclic Compounds

, volume 56 , issue 7 , pages 837-847

Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride

Oleg А Rakitin ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia |

Nanotechnology Research and Education Center, South Ural State University, Chelyabinsk, Russia |

Publication type: Journal Article

Publication date: 2020-07-01

Springer Nature

Chemistry of Heterocyclic Compounds

scimago Q4

wos Q4

SJR: 0.243

CiteScore: 2.7

Impact factor: 1.0

ISSN: 00093122, 15738353

DOI: 10.1007/s10593-020-02740-2

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Organic Chemistry

Abstract

This review compiles and summarizes approaches to the preparation of heterocyclic systems containing sulfur atoms based on the reactions of disulfur dichloride which acts as an electrophilic reagent. It is shown that as a result of these transformations heterocycles with different numbers of sulfur atoms can be synthesized: 1,2,5-thiadiazoles, 1,2- and 1,4-thiazines, 1,2-dithiols, 1,2,3-dithiazoles, 1,2,3,4,5-pentathiepines, 1,2,3,4,5,6,7-heptathiocanes, and many others. The yields of the products of these reactions depend to a significant extent on the ratio of the reactants, the nature of the solvent, the base used, and the temperature. The exceptional role of disulfur dichloride in the synthesis of various sulfur-containing heterocycles is shown.

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Khisamov Radmir

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Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Novosibirsk State University

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Rakitin O. А. Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride // Chemistry of Heterocyclic Compounds. 2020. Vol. 56. No. 7. pp. 837-847.

GOST all authors (up to 50) Copy

Rakitin O. А. Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride // Chemistry of Heterocyclic Compounds. 2020. Vol. 56. No. 7. pp. 837-847.

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RIS Copy

TY - JOUR

DO - 10.1007/s10593-020-02740-2

UR - https://doi.org/10.1007/s10593-020-02740-2

TI - Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride

T2 - Chemistry of Heterocyclic Compounds

AU - Rakitin, Oleg А

PY - 2020

DA - 2020/07/01

PB - Springer Nature

SP - 837-847

IS - 7

VL - 56

SN - 0009-3122

SN - 1573-8353

ER -

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@article{2020_Rakitin,

author = {Oleg А Rakitin},

title = {Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride},

journal = {Chemistry of Heterocyclic Compounds},

year = {2020},

volume = {56},

publisher = {Springer Nature},

month = {jul},

url = {https://doi.org/10.1007/s10593-020-02740-2},

number = {7},

pages = {837--847},

doi = {10.1007/s10593-020-02740-2}

}

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Rakitin, Oleg А.. “Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride.” Chemistry of Heterocyclic Compounds, vol. 56, no. 7, Jul. 2020, pp. 837-847. https://doi.org/10.1007/s10593-020-02740-2.