NMR Parameters of Imidazolium Ionic Liquids as Indicators of Their State and Properties in Aqueous Solutions
Publication type: Journal Article
Publication date: 2020-11-28
scimago Q3
wos Q4
SJR: 0.279
CiteScore: 2.3
Impact factor: 1.3
ISSN: 00959782, 15728927
Biochemistry
Physical and Theoretical Chemistry
Molecular Biology
Biophysics
Abstract
Seven 1-methylimidazolium-based ionic liquids (ILs) and their aqueous solutions were systematically investigated in order to explore how the NMR spectroscopic properties (chemical shifts, spin–spin coupling constants) are connected or correlated with several physical and chemical properties (density, viscosity, water content, etc.) of ILs and their aqueous mixtures. 1H and 13C NMR chemical shifts of ILs vary markedly depending on different anions, alkyl chain length, and water content. Addition of water affected the NMR parameters in various manners, altering several of them significantly, while others did not change distinctly. Dissimilar behavior of NMR parameters in various solvents at various concentrations allows one to conclude that they reflect several contributions from different properties of ILs and can be used for deep structural investigations.
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Shahkhatuni A. A. et al. NMR Parameters of Imidazolium Ionic Liquids as Indicators of Their State and Properties in Aqueous Solutions // Journal of Solution Chemistry. 2020. Vol. 50. No. 1. pp. 90-104.
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Shahkhatuni A. A., Shahkhatuni A. G., Mamyan S. S., Ananikov V. P., Harutyunyan A. S. NMR Parameters of Imidazolium Ionic Liquids as Indicators of Their State and Properties in Aqueous Solutions // Journal of Solution Chemistry. 2020. Vol. 50. No. 1. pp. 90-104.
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TY - JOUR
DO - 10.1007/s10953-020-01044-5
UR - https://doi.org/10.1007/s10953-020-01044-5
TI - NMR Parameters of Imidazolium Ionic Liquids as Indicators of Their State and Properties in Aqueous Solutions
T2 - Journal of Solution Chemistry
AU - Shahkhatuni, Astghik A
AU - Shahkhatuni, A G
AU - Mamyan, S S
AU - Ananikov, V P
AU - Harutyunyan, A S
PY - 2020
DA - 2020/11/28
PB - Springer Nature
SP - 90-104
IS - 1
VL - 50
SN - 0095-9782
SN - 1572-8927
ER -
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@article{2020_Shahkhatuni,
author = {Astghik A Shahkhatuni and A G Shahkhatuni and S S Mamyan and V P Ananikov and A S Harutyunyan},
title = {NMR Parameters of Imidazolium Ionic Liquids as Indicators of Their State and Properties in Aqueous Solutions},
journal = {Journal of Solution Chemistry},
year = {2020},
volume = {50},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s10953-020-01044-5},
number = {1},
pages = {90--104},
doi = {10.1007/s10953-020-01044-5}
}
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MLA
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Shahkhatuni, Astghik A., et al. “NMR Parameters of Imidazolium Ionic Liquids as Indicators of Their State and Properties in Aqueous Solutions.” Journal of Solution Chemistry, vol. 50, no. 1, Nov. 2020, pp. 90-104. https://doi.org/10.1007/s10953-020-01044-5.
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