Kinetics and Catalysis

, volume 46 , issue 1 , pages 52-55

Mechanism of one-electron reactions of copper(I) chloride complexes with chlorohydrocarbons

D N Kharitonov ¹

E. N. Golubeva ¹

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Department of Chemistry, Moscow State University, Moscow, Russia |

Publication type: Journal Article

Publication date: 2005-01-01

Pleiades Publishing

Kinetics and Catalysis

scimago Q3

wos Q4

SJR: 0.260

CiteScore: 1.9

Impact factor: 1.4

ISSN: 00231584, 16083210

DOI: 10.1007/s10975-005-0041-8

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General Chemistry

Catalysis

Computer Science Applications

Modeling and Simulation

Abstract

The reactivity of chlorohydrocarbons with different electron affinities (A e) and C-Cl bond dissociation energies (E C-Cl) in the oxidation of copper(I) chloride complexes was studied. The rate of oxidation depends only on Ae. Chain initiation, involving Cu(I), occurs by an electron-transfer mechanism.

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Zubanova Ekaterina

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PhD in Chemistry

15 publications, 79 citations

h-index: 6

Lomonosov Moscow State University

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Kharitonov D. N., Golubeva E. N. Mechanism of one-electron reactions of copper(I) chloride complexes with chlorohydrocarbons // Kinetics and Catalysis. 2005. Vol. 46. No. 1. pp. 52-55.

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Kharitonov D. N., Golubeva E. N. Mechanism of one-electron reactions of copper(I) chloride complexes with chlorohydrocarbons // Kinetics and Catalysis. 2005. Vol. 46. No. 1. pp. 52-55.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1007/s10975-005-0041-8

UR - https://doi.org/10.1007/s10975-005-0041-8

TI - Mechanism of one-electron reactions of copper(I) chloride complexes with chlorohydrocarbons

T2 - Kinetics and Catalysis

AU - Kharitonov, D N

AU - Golubeva, E. N.

PY - 2005

DA - 2005/01/01

PB - Pleiades Publishing

SP - 52-55

IS - 1

VL - 46

SN - 0023-1584

SN - 1608-3210

ER -

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@article{2005_Kharitonov,

author = {D N Kharitonov and E. N. Golubeva},

title = {Mechanism of one-electron reactions of copper(I) chloride complexes with chlorohydrocarbons},

journal = {Kinetics and Catalysis},

year = {2005},

volume = {46},

publisher = {Pleiades Publishing},

month = {jan},

url = {https://doi.org/10.1007/s10975-005-0041-8},

number = {1},

pages = {52--55},

doi = {10.1007/s10975-005-0041-8}

}

MLA

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Kharitonov, D. N., and E. N. Golubeva. “Mechanism of one-electron reactions of copper(I) chloride complexes with chlorohydrocarbons.” Kinetics and Catalysis, vol. 46, no. 1, Jan. 2005, pp. 52-55. https://doi.org/10.1007/s10975-005-0041-8.