Kinetics and Catalysis

, volume 45 , issue 6 , pages 867-869

Competitive complexation in the copper(II) chloride-N,N-dimethylformamide- aerosil system

E. N. Golubeva ¹

N A Zubareva ¹

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Faculty of Chemistry, Moscow State University, Moscow, Russia |

Publication type: Journal Article

Publication date: 2004-11-01

Pleiades Publishing

Kinetics and Catalysis

scimago Q3

wos Q4

SJR: 0.260

CiteScore: 1.9

Impact factor: 1.4

ISSN: 00231584, 16083210

DOI: 10.1007/s10975-005-0052-5

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General Chemistry

Catalysis

Computer Science Applications

Modeling and Simulation

Abstract

Competitive complexation in the copper(II) chloride-N,N-dimethylformamide (DMF)-Aerosil system was studied by IR spectroscopy. It was found that adsorption from organic solutions containing copper(II) chloride and DMF resulted in the formation of the following three types of DMF complexes: self-associates of DMF, DMF complexes with surface hydroxyl groups, and DMF complexes with Cu(II) ions. The removal of DMF resulted in the sequential degradation of, initially, self-associates; next, complexes with silanol groups; and, finally, complexes with copper ions.

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Golubeva E. N., Zubareva N. A. Competitive complexation in the copper(II) chloride-N,N-dimethylformamide- aerosil system // Kinetics and Catalysis. 2004. Vol. 45. No. 6. pp. 867-869.

GOST all authors (up to 50) Copy

Golubeva E. N., Zubareva N. A. Competitive complexation in the copper(II) chloride-N,N-dimethylformamide- aerosil system // Kinetics and Catalysis. 2004. Vol. 45. No. 6. pp. 867-869.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1007/s10975-005-0052-5

UR - https://doi.org/10.1007/s10975-005-0052-5

TI - Competitive complexation in the copper(II) chloride-N,N-dimethylformamide- aerosil system

T2 - Kinetics and Catalysis

AU - Golubeva, E. N.

AU - Zubareva, N A

PY - 2004

DA - 2004/11/01

PB - Pleiades Publishing

SP - 867-869

IS - 6

VL - 45

SN - 0023-1584

SN - 1608-3210

ER -

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@article{2004_Golubeva,

author = {E. N. Golubeva and N A Zubareva},

title = {Competitive complexation in the copper(II) chloride-N,N-dimethylformamide- aerosil system},

journal = {Kinetics and Catalysis},

year = {2004},

volume = {45},

publisher = {Pleiades Publishing},

month = {nov},

url = {https://doi.org/10.1007/s10975-005-0052-5},

number = {6},

pages = {867--869},

doi = {10.1007/s10975-005-0052-5}

}

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Golubeva, E. N., and N A Zubareva. “Competitive complexation in the copper(II) chloride-N,N-dimethylformamide- aerosil system.” Kinetics and Catalysis, vol. 45, no. 6, Nov. 2004, pp. 867-869. https://doi.org/10.1007/s10975-005-0052-5.