Electrochemical study of the sequence of reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one and its analogs
Publication type: Journal Article
Publication date: 2006-09-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The electrochemical behavior of a series of halogen-containing cyclohexa-2,5-dien-1-ones at the glassy-carbon electrode in DMF was studied. The reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one first results in the elimination of the carbonylallylic bromine atoms, then the carbonylic bromine atom is elimi-nated, and finally, the neopentylic chlorine atoms are eliminated.
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Gavrilova G. V. et al. Electrochemical study of the sequence of reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one and its analogs // Russian Chemical Bulletin. 2006. Vol. 55. No. 9. pp. 1617-1623.
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Gavrilova G. V., Moiseeva A. A., Beloglazkina E. K., Gavrilov A., Butin K. Electrochemical study of the sequence of reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one and its analogs // Russian Chemical Bulletin. 2006. Vol. 55. No. 9. pp. 1617-1623.
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TY - JOUR
DO - 10.1007/s11172-006-0463-0
UR - http://link.springer.com/10.1007/s11172-006-0463-0
TI - Electrochemical study of the sequence of reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one and its analogs
T2 - Russian Chemical Bulletin
AU - Gavrilova, G V
AU - Moiseeva, A A
AU - Beloglazkina, E K
AU - Gavrilov, A.A.
AU - Butin, K.P.
PY - 2006
DA - 2006/09/01
PB - Springer Nature
SP - 1617-1623
IS - 9
VL - 55
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2006_Gavrilova,
author = {G V Gavrilova and A A Moiseeva and E K Beloglazkina and A.A. Gavrilov and K.P. Butin},
title = {Electrochemical study of the sequence of reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one and its analogs},
journal = {Russian Chemical Bulletin},
year = {2006},
volume = {55},
publisher = {Springer Nature},
month = {sep},
url = {http://link.springer.com/10.1007/s11172-006-0463-0},
number = {9},
pages = {1617--1623},
doi = {10.1007/s11172-006-0463-0}
}
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Gavrilova, G. V., et al. āElectrochemical study of the sequence of reductive dehalogenation of 2-bromo-5-dibromomethyl-4-dichloromethyl-4-methylcyclohexa-2,5-dien-1-one and its analogs.ā Russian Chemical Bulletin, vol. 55, no. 9, Sep. 2006, pp. 1617-1623. http://link.springer.com/10.1007/s11172-006-0463-0.
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