Thermal decomposition of dinuclear complexes LM(μ-OOCR)4ML (L is α-substituted pyridine)
I.G. Fomina
1
,
Zh V Dobrokhotova
1
,
M. A. Kiskin
1
,
G.G. Aleksandrov
1
,
O Yu Proshenkina
1
,
A L Emelina
2
,
V. N. Ikorskii
3
,
V. M. Novotortsev
1
,
Publication type: Journal Article
Publication date: 2007-09-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The solid-state thermal decomposition of the tetrabridged dinuclear MnII, FeII, CoII, NiII, and CuII pivalate complexes with apical α-substituted pyridine ligands containing different substituents (2,3-dimethylpyridine or quinoline) was studied by differential scanning calorimetry and thermogravimetry. The decomposition of the CoII complexes is accompanied by the aggregation to form the volatile octanuclear complex Co8(μ4-O)2(μn-OOCCMe3)12, where n = 2 or 3, whereas the thermolysis of the MnII, FeII, NiII, and CuII complexes is accompanied by the degradation of the starting compounds, the phase composition of the decomposition products being substantially dependent on the nature of metal and the apical organic ligand.
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Fomina I. et al. Thermal decomposition of dinuclear complexes LM(μ-OOCR)4ML (L is α-substituted pyridine) // Russian Chemical Bulletin. 2007. Vol. 56. No. 9. pp. 1712-1721.
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Fomina I., Dobrokhotova Z. V., Kiskin M. A., Aleksandrov G., Proshenkina O. Yu., Emelina A. L., Ikorskii V. N., Novotortsev V. M., Eremenko I. L. Thermal decomposition of dinuclear complexes LM(μ-OOCR)4ML (L is α-substituted pyridine) // Russian Chemical Bulletin. 2007. Vol. 56. No. 9. pp. 1712-1721.
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TY - JOUR
DO - 10.1007/s11172-007-0266-y
UR - https://doi.org/10.1007/s11172-007-0266-y
TI - Thermal decomposition of dinuclear complexes LM(μ-OOCR)4ML (L is α-substituted pyridine)
T2 - Russian Chemical Bulletin
AU - Fomina, I.G.
AU - Dobrokhotova, Zh V
AU - Kiskin, M. A.
AU - Aleksandrov, G.G.
AU - Proshenkina, O Yu
AU - Emelina, A L
AU - Ikorskii, V. N.
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2007
DA - 2007/09/01
PB - Springer Nature
SP - 1712-1721
IS - 9
VL - 56
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2007_Fomina,
author = {I.G. Fomina and Zh V Dobrokhotova and M. A. Kiskin and G.G. Aleksandrov and O Yu Proshenkina and A L Emelina and V. N. Ikorskii and V. M. Novotortsev and I. L. Eremenko},
title = {Thermal decomposition of dinuclear complexes LM(μ-OOCR)4ML (L is α-substituted pyridine)},
journal = {Russian Chemical Bulletin},
year = {2007},
volume = {56},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s11172-007-0266-y},
number = {9},
pages = {1712--1721},
doi = {10.1007/s11172-007-0266-y}
}
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MLA
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Fomina, I.G., et al. “Thermal decomposition of dinuclear complexes LM(μ-OOCR)4ML (L is α-substituted pyridine).” Russian Chemical Bulletin, vol. 56, no. 9, Sep. 2007, pp. 1712-1721. https://doi.org/10.1007/s11172-007-0266-y.