New isomers of trifluoromethylated fullerene: C60(CF3)12 and C60(CF3)14
N A Samokhvalova
1
,
P A Khavrel
1
,
A. A. Goryunkov
1
,
I N Ioffe
1
,
V L Karnatsevich
2
,
L.N. Sidorov
1
,
E Kemnitz
3
,
S I Troyanova
1
2
Fullerene Center, Nizhny Novgorod, Russian Federation
|
Publication type: Journal Article
Publication date: 2008-12-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
HPLC separation of the products of high-temperature reaction of a sublimed mixture of C60–C70 (10: 1) with CF3I in a sealed ampoule allowed isolation and determination of molecular structures (X-ray crystallography and 19F NMR) of two new isomers of C60(CF3)12 and one isomer of C60(CF3)14. These isomers are characterized by low relative formation energies, which suggests that the trifluoromethylation process is basically under the thermodynamic control.
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Samokhvalova N. A. et al. New isomers of trifluoromethylated fullerene: C60(CF3)12 and C60(CF3)14 // Russian Chemical Bulletin. 2008. Vol. 57. No. 12. pp. 2526-2534.
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Samokhvalova N. A., Khavrel P. A., Goryunkov A. A., Ioffe I. N., Karnatsevich V. L., Sidorov L., Kemnitz E., Troyanova S. I. New isomers of trifluoromethylated fullerene: C60(CF3)12 and C60(CF3)14 // Russian Chemical Bulletin. 2008. Vol. 57. No. 12. pp. 2526-2534.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11172-008-0363-6
UR - https://doi.org/10.1007/s11172-008-0363-6
TI - New isomers of trifluoromethylated fullerene: C60(CF3)12 and C60(CF3)14
T2 - Russian Chemical Bulletin
AU - Samokhvalova, N A
AU - Khavrel, P A
AU - Goryunkov, A. A.
AU - Ioffe, I N
AU - Karnatsevich, V L
AU - Sidorov, L.N.
AU - Kemnitz, E
AU - Troyanova, S I
PY - 2008
DA - 2008/12/01
PB - Springer Nature
SP - 2526-2534
IS - 12
VL - 57
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2008_Samokhvalova,
author = {N A Samokhvalova and P A Khavrel and A. A. Goryunkov and I N Ioffe and V L Karnatsevich and L.N. Sidorov and E Kemnitz and S I Troyanova},
title = {New isomers of trifluoromethylated fullerene: C60(CF3)12 and C60(CF3)14},
journal = {Russian Chemical Bulletin},
year = {2008},
volume = {57},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/s11172-008-0363-6},
number = {12},
pages = {2526--2534},
doi = {10.1007/s11172-008-0363-6}
}
Cite this
MLA
Copy
Samokhvalova, N. A., et al. “New isomers of trifluoromethylated fullerene: C60(CF3)12 and C60(CF3)14.” Russian Chemical Bulletin, vol. 57, no. 12, Dec. 2008, pp. 2526-2534. https://doi.org/10.1007/s11172-008-0363-6.