New dioxygen-inert triphenylantimony(v) catecholate complexes based on o-quinones with electron-withdrawing groups
Тип публикации: Journal Article
Дата публикации: 2009-03-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
New triphenylantimony(v) catecholate complexes were synthesized by oxidative addition of sterically hindered o-benzoquinones containing electron-withdrawing substituents in different positions of the carbon ring to triphenylantimony. The complexes were characterized using IR spectroscopy, NMR spectroscopy, and cyclic voltammetry. The oxygen-inertness of the complexes is shown by NMR spectroscopy and electrochemical studies. The introduction of electron-withdrawing substituents to the catecholate ligand shifts the first oxidation potential of the complexes to the electropositive region and thus deactivates the triphenylantimony(v) catecholate complexes in the reaction with molecular oxygen.
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Poddelsky A. I. et al. New dioxygen-inert triphenylantimony(v) catecholate complexes based on o-quinones with electron-withdrawing groups // Russian Chemical Bulletin. 2009. Vol. 58. No. 3. pp. 532-537.
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Poddelsky A. I., Smolyaninov I. V., Kurskii Y. A., Berberova N. T., Cherkasov V. K., Abakumov G. A. New dioxygen-inert triphenylantimony(v) catecholate complexes based on o-quinones with electron-withdrawing groups // Russian Chemical Bulletin. 2009. Vol. 58. No. 3. pp. 532-537.
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TY - JOUR
DO - 10.1007/s11172-009-0052-0
UR - https://doi.org/10.1007/s11172-009-0052-0
TI - New dioxygen-inert triphenylantimony(v) catecholate complexes based on o-quinones with electron-withdrawing groups
T2 - Russian Chemical Bulletin
AU - Poddelsky, A I
AU - Smolyaninov, I V
AU - Kurskii, Yu. A.
AU - Berberova, N T
AU - Cherkasov, V. K.
AU - Abakumov, G. A.
PY - 2009
DA - 2009/03/01
PB - Springer Nature
SP - 532-537
IS - 3
VL - 58
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2009_Poddelsky,
author = {A I Poddelsky and I V Smolyaninov and Yu. A. Kurskii and N T Berberova and V. K. Cherkasov and G. A. Abakumov},
title = {New dioxygen-inert triphenylantimony(v) catecholate complexes based on o-quinones with electron-withdrawing groups},
journal = {Russian Chemical Bulletin},
year = {2009},
volume = {58},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s11172-009-0052-0},
number = {3},
pages = {532--537},
doi = {10.1007/s11172-009-0052-0}
}
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MLA
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Poddelsky, A. I., et al. “New dioxygen-inert triphenylantimony(v) catecholate complexes based on o-quinones with electron-withdrawing groups.” Russian Chemical Bulletin, vol. 58, no. 3, Mar. 2009, pp. 532-537. https://doi.org/10.1007/s11172-009-0052-0.
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