Russian Chemical Bulletin

, том 59 , издание 3 , страницы 539-543

A complex of gold(I) benzenethiolate with isocyanide: Synthesis and crystal and molecular structures

Тип публикации: Journal Article

Дата публикации: 2010-03-01

Springer Nature

Russian Chemical Bulletin

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БС2

SJR: 0.305

CiteScore: 2.8

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ISSN: 10665285, 15739171

DOI: 10.1007/s11172-010-0143-y

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General Chemistry

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Abstract2,6-Dimethylphenyl isocyanide forms complexes with gold( I) chloride (complex 4) and gold(I) benzenethiolate (complex 5) but forms no stable complexes with gold alkanethiolates. A reaction of complex 5 with tetramethylthiuram disulfide yields gold(I) dimethyldithiocar-bamate. Stable gold(III) derivatives cannot be obtained in such a way. Shortened intermolecular Au...Au contacts in complexes 4 and 5 (X-ray diffraction) suggest the presence of “aurophilic” interactions in them.

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Dyadchenko V. P. et al. A complex of gold(I) benzenethiolate with isocyanide: Synthesis and crystal and molecular structures // Russian Chemical Bulletin. 2010. Vol. 59. No. 3. pp. 539-543.

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Dyadchenko V. P., Belov N. M., Dyadchenko M. A., Slovokhotov Y. L., Banaru A. M., Lemenovskii D. A. A complex of gold(I) benzenethiolate with isocyanide: Synthesis and crystal and molecular structures // Russian Chemical Bulletin. 2010. Vol. 59. No. 3. pp. 539-543.

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TY - JOUR

DO - 10.1007/s11172-010-0143-y

UR - http://link.springer.com/10.1007/s11172-010-0143-y

TI - A complex of gold(I) benzenethiolate with isocyanide: Synthesis and crystal and molecular structures

T2 - Russian Chemical Bulletin

AU - Dyadchenko, V P

AU - Belov, N M

AU - Dyadchenko, M A

AU - Slovokhotov, Yu. L.

AU - Banaru, A M

AU - Lemenovskii, D A

PY - 2010

DA - 2010/03/01

PB - Springer Nature

SP - 539-543

IS - 3

VL - 59

SN - 1066-5285

SN - 1573-9171

ER -

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@article{2010_Dyadchenko,

author = {V P Dyadchenko and N M Belov and M A Dyadchenko and Yu. L. Slovokhotov and A M Banaru and D A Lemenovskii},

title = {A complex of gold(I) benzenethiolate with isocyanide: Synthesis and crystal and molecular structures},

journal = {Russian Chemical Bulletin},

year = {2010},

volume = {59},

publisher = {Springer Nature},

month = {mar},

url = {http://link.springer.com/10.1007/s11172-010-0143-y},

number = {3},

pages = {539--543},

doi = {10.1007/s11172-010-0143-y}

}

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Dyadchenko, V. P., et al. “A complex of gold(I) benzenethiolate with isocyanide: Synthesis and crystal and molecular structures.” Russian Chemical Bulletin, vol. 59, no. 3, Mar. 2010, pp. 539-543. http://link.springer.com/10.1007/s11172-010-0143-y.