том 59 издание 6 страницы 1186-1191

Formation of polynuclear architectures with copper atoms and 1,1-cyclohexanediacetate anions

Тип публикацииJournal Article
Дата публикации2010-06-01
scimago Q3
БС2
SJR0.305
CiteScore2.8
Impact factor
ISSN10665285, 15739171
General Chemistry
Краткое описание
The reaction of copper nitrate Cu(NO3)2·3H2O with potassium salt of 1,1-cyclohexanediacetic acid (H2CHDAA) in an EtOH-toluene mixture affords the polymeric complex {[(EtOH)2Cu2(CHDAA)2]·EtOHn (1). The addition of pyridine to the Cu(NO3)2·3H2O-K2CHDAA reaction system in an EtOH-MeCN mixture results in the isolation of the unusual octadecanuclear heterometallic cluster [K2(η1-H2O)6(η1-py)8Cu16-(η1-OH)2(μ4-CHDAA)16]·EtOH·MeCN·3H2O (2). In complex 2, the hexadecanuclear metal carboxylate dianion (η1-H2O)6(η1-py)8Cu16(η1-OH)2(μ4-CHDAA)16 acts as the metal-containing macropolycyclic ligand. The newly synthesized compounds 1 and 2 were characterized by X-ray diffraction and EPR.
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Russian Chemical Bulletin
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Russian Journal of Inorganic Chemistry
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Journal of Cluster Science
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Journal of Molecular Structure
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Journal of Coordination Chemistry
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Inorganic Chemistry Communication
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Zauzolkova N. V. et al. Formation of polynuclear architectures with copper atoms and 1,1-cyclohexanediacetate anions // Russian Chemical Bulletin. 2010. Vol. 59. No. 6. pp. 1186-1191.
ГОСТ со всеми авторами (до 50) Скопировать
Zauzolkova N. V., Nikiforova M. E., Sidorov A. A., Apolonskaya I. A., Fedin M. V., Minin V. V., Rotov A. V., Ugolkova E. A., Kiskin M. A., Aleksandrov G., Novotortsev V. M., Eremenko I. L. Formation of polynuclear architectures with copper atoms and 1,1-cyclohexanediacetate anions // Russian Chemical Bulletin. 2010. Vol. 59. No. 6. pp. 1186-1191.
RIS |
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TY - JOUR
DO - 10.1007/s11172-010-0221-1
UR - https://doi.org/10.1007/s11172-010-0221-1
TI - Formation of polynuclear architectures with copper atoms and 1,1-cyclohexanediacetate anions
T2 - Russian Chemical Bulletin
AU - Zauzolkova, N V
AU - Nikiforova, M E
AU - Sidorov, A. A.
AU - Apolonskaya, I A
AU - Fedin, M V
AU - Minin, V V
AU - Rotov, A V
AU - Ugolkova, E. A.
AU - Kiskin, M. A.
AU - Aleksandrov, G.G.
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2010
DA - 2010/06/01
PB - Springer Nature
SP - 1186-1191
IS - 6
VL - 59
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
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@article{2010_Zauzolkova,
author = {N V Zauzolkova and M E Nikiforova and A. A. Sidorov and I A Apolonskaya and M V Fedin and V V Minin and A V Rotov and E. A. Ugolkova and M. A. Kiskin and G.G. Aleksandrov and V. M. Novotortsev and I. L. Eremenko},
title = {Formation of polynuclear architectures with copper atoms and 1,1-cyclohexanediacetate anions},
journal = {Russian Chemical Bulletin},
year = {2010},
volume = {59},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-010-0221-1},
number = {6},
pages = {1186--1191},
doi = {10.1007/s11172-010-0221-1}
}
MLA
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Zauzolkova, N. V., et al. “Formation of polynuclear architectures with copper atoms and 1,1-cyclohexanediacetate anions.” Russian Chemical Bulletin, vol. 59, no. 6, Jun. 2010, pp. 1186-1191. https://doi.org/10.1007/s11172-010-0221-1.