Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes
R A Polunin
1
,
S V Kolotilov
1
,
M. A. Kiskin
2
,
K S Gavrilenko
1
,
L. Ouahab
3
,
I. L. Eremenko
2
,
V. M. Novotortsev
2
,
V V Pavlishchuk
1
1
L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of the Ukraine, Kiev, Ukraine
|
Publication type: Journal Article
Publication date: 2010-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reaction of trinuclear acetate complexes Fe2MO(AcO)6(H2O)3 (M = Ni2+, Co2+) with 4,4′-bipyridine (bpy) results, depending on the reaction conditions, in porous coordination polymers with the composition Fe2MO(AcO)6(bpy)1.5 (with retention of the metal core Fe2MO(AcO)6) or nonporous coordination polymers with the composition M2(AcO)4(bpy)2 (with destruction of the metal core Fe2MO(AcO)6). The adsorption and desorption properties of the compounds Fe2MO(AcO)6(bpy)1.5 with respect to nitrogen and hydrogen were studied. The reaction of hexanuclear benzoate complex Mn6O2(PhCOO)10(MeCN)4 with bpy or trans-1,2-bis(4-pyridyl)ethylene (bpe) in DMF results in destruction of the metal core Mn6O2(PhCOO)10 and formation of nonporous coordination polymers, while the pivalate complex Mn6O2(Piv)10(EtOH)3(HPiv) under the same conditions gives rise to the coordination polymer containing Mn6O2(Piv)10 structural blocks.
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Polunin R. A. et al. Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes // Russian Chemical Bulletin. 2010. Vol. 59. No. 6. pp. 1217-1224.
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Polunin R. A., Kolotilov S. V., Kiskin M. A., Gavrilenko K. S., Ouahab L., Eremenko I. L., Novotortsev V. M., Pavlishchuk V. V. Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes // Russian Chemical Bulletin. 2010. Vol. 59. No. 6. pp. 1217-1224.
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RIS
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TY - JOUR
DO - 10.1007/s11172-010-0224-y
UR - https://doi.org/10.1007/s11172-010-0224-y
TI - Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes
T2 - Russian Chemical Bulletin
AU - Polunin, R A
AU - Kolotilov, S V
AU - Kiskin, M. A.
AU - Gavrilenko, K S
AU - Ouahab, L.
AU - Eremenko, I. L.
AU - Novotortsev, V. M.
AU - Pavlishchuk, V V
PY - 2010
DA - 2010/06/01
PB - Springer Nature
SP - 1217-1224
IS - 6
VL - 59
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2010_Polunin,
author = {R A Polunin and S V Kolotilov and M. A. Kiskin and K S Gavrilenko and L. Ouahab and I. L. Eremenko and V. M. Novotortsev and V V Pavlishchuk},
title = {Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes},
journal = {Russian Chemical Bulletin},
year = {2010},
volume = {59},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-010-0224-y},
number = {6},
pages = {1217--1224},
doi = {10.1007/s11172-010-0224-y}
}
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Polunin, R. A., et al. “Structures and sorption properties of the coordination polymers built up of 3d metal carboxylate polynuclear complexes.” Russian Chemical Bulletin, vol. 59, no. 6, Jun. 2010, pp. 1217-1224. https://doi.org/10.1007/s11172-010-0224-y.
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