Hydrosilylation of non-1-ene with phenylsilane in the presence of yttrium and lutetium bisguanidinate hydride complexes
Тип публикации: Journal Article
Дата публикации: 2010-09-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
Some regularities of hydrosilylation of non-1-ene with phenylsilane catalyzed by yttrium and lutetium bisguanidinate hydride complexes {[(Me3Si)2NC(NR)2]2Ln(μ-H)}2 (Ln = Y, Lu; R = Pri, Cy (Cy is cyclohexyl)) have been studied. The addition of PhSiH3 to the double bond of non-1-ene in the presence of a {[(Me3Si)2NC(NPri)2]2Y(μ-H)}2 complex has the first order in olefin and zero order in phenylsilane. This indicates that the insertion of non-1-ene into the Ln-H bond is a rate determining stage of the process, whereas the metathesis of the Ln-C σ-bond upon the action of phenylsilane proceeds rapidly. The first example of successive double alkylation of phenylsilane with an olefin catalyzed by a rare-earth metal complex with the formation of tertiary silane has been discovered.
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Lyubov D. M. et al. Hydrosilylation of non-1-ene with phenylsilane in the presence of yttrium and lutetium bisguanidinate hydride complexes // Russian Chemical Bulletin. 2010. Vol. 59. No. 9. pp. 1765-1770.
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Lyubov D. M., Shavyrin A. S., Kurskii Y. A., Trifonov A. A. Hydrosilylation of non-1-ene with phenylsilane in the presence of yttrium and lutetium bisguanidinate hydride complexes // Russian Chemical Bulletin. 2010. Vol. 59. No. 9. pp. 1765-1770.
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TY - JOUR
DO - 10.1007/s11172-010-0310-1
UR - https://doi.org/10.1007/s11172-010-0310-1
TI - Hydrosilylation of non-1-ene with phenylsilane in the presence of yttrium and lutetium bisguanidinate hydride complexes
T2 - Russian Chemical Bulletin
AU - Lyubov, D M
AU - Shavyrin, A S
AU - Kurskii, Yu. A.
AU - Trifonov, A A
PY - 2010
DA - 2010/09/01
PB - Springer Nature
SP - 1765-1770
IS - 9
VL - 59
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2010_Lyubov,
author = {D M Lyubov and A S Shavyrin and Yu. A. Kurskii and A A Trifonov},
title = {Hydrosilylation of non-1-ene with phenylsilane in the presence of yttrium and lutetium bisguanidinate hydride complexes},
journal = {Russian Chemical Bulletin},
year = {2010},
volume = {59},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s11172-010-0310-1},
number = {9},
pages = {1765--1770},
doi = {10.1007/s11172-010-0310-1}
}
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Lyubov, D. M., et al. “Hydrosilylation of non-1-ene with phenylsilane in the presence of yttrium and lutetium bisguanidinate hydride complexes.” Russian Chemical Bulletin, vol. 59, no. 9, Sep. 2010, pp. 1765-1770. https://doi.org/10.1007/s11172-010-0310-1.
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