Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers
Publication type: Journal Article
Publication date: 2011-02-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reaction of cobalt(II) chloride with 2-hydroxypyridine (Hhp) and lithium pivalate in acetonitrile affords the 1D polymer [Li3CoCl(μ-Piv)(μ3-Piv)2(μ3,η2-Piv)(μ-Hhp)2(η1-HPiv)]n, in which the repeating units are linked by bridging pyridone molecules. The reaction of cobalt nitrate hexahydrate with 2-hydroxy-6-methylpyridine (Hmhp) in the presence of the deprotonating agent (Et3N) resulted in the crystallization of the 1D polymer of the composition [Li2Co7(μ3-OH)2(μ3-Piv)3(μ-Piv)2(μ3,η2-mhp)5(μ,η2-mhp)2(μ3-mhp)(μ,η2-NO3)·2MeCN]n, in which the bulky metal fragments {Li2Co7(OH)2(Piv)5)(mhp)8} are linked together through the lithium atoms by chelate bridging nitrate anions. The resulting 1D polymers were characterized by X-ray diffraction, and their magnetic properties were investigated.
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Total citations:
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Citations from 2024:
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Zauzolkova N. V. et al. Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers // Russian Chemical Bulletin. 2011. Vol. 60. No. 2. pp. 273-279.
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Zauzolkova N. V., Nikiforova M. E., Kiskin M. A., Bogomyakov A. S., Sidorov A. A., Eremenko I. L. Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers // Russian Chemical Bulletin. 2011. Vol. 60. No. 2. pp. 273-279.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11172-011-0046-6
UR - https://doi.org/10.1007/s11172-011-0046-6
TI - Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers
T2 - Russian Chemical Bulletin
AU - Zauzolkova, N V
AU - Nikiforova, M E
AU - Kiskin, M. A.
AU - Bogomyakov, A S
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2011
DA - 2011/02/01
PB - Springer Nature
SP - 273-279
IS - 2
VL - 60
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2011_Zauzolkova,
author = {N V Zauzolkova and M E Nikiforova and M. A. Kiskin and A S Bogomyakov and A. A. Sidorov and I. L. Eremenko},
title = {Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers},
journal = {Russian Chemical Bulletin},
year = {2011},
volume = {60},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s11172-011-0046-6},
number = {2},
pages = {273--279},
doi = {10.1007/s11172-011-0046-6}
}
Cite this
MLA
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Zauzolkova, N. V., et al. “Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers.” Russian Chemical Bulletin, vol. 60, no. 2, Feb. 2011, pp. 273-279. https://doi.org/10.1007/s11172-011-0046-6.