Synthesis, structure, and magnetic properties of heterometallic trinuclear complexes {MII—LnIII—MII} (MII = Ni, Cu; LnIII = La, Pr, Sm, Eu, Gd)
N P Burkovskaya
1
,
E V Orlova
1
,
M. A. Kiskin
1
,
N. N. Efimov
1
,
A S Bogomyakov
2
,
M V Fedin
2
,
S V Kolotilov
3
,
V V Minin
1
,
G.G. Aleksandrov
1
,
A. A. Sidorov
1
,
V.I. Ovcharenko
2
,
V. M. Novotortsev
1
,
3
L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of the Ukraine, Kiev, Ukraine
|
Publication type: Journal Article
Publication date: 2011-12-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Trinuclear heterometallic complexes containing the {M2Ln(Piv)6(NO3)} (MII = Ni, Cu; LnIII = Nd, Pr, Sm, Eu, Gd; Piv− is the anion of pivalic acid) and {Cu2Ln(Piv)8)]− (LnIII = Eu, Gd) metal cores were synthesized, their structures and magnetic properties were studied. For the most compounds, it was shown that their magnetic properties can be interpreted taking no interaction of the 3d-metal ions and a lanthanide into account. Ferromagnetic exchange interactions were found to exist between the unpaired electrons of the paramagnetic centers in the exchange clusters of the gadolinium-containing heterometallic complexes {M-Gd-M} (M = Ni or Cu).
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Burkovskaya N. P. et al. Synthesis, structure, and magnetic properties of heterometallic trinuclear complexes {MII—LnIII—MII} (MII = Ni, Cu; LnIII = La, Pr, Sm, Eu, Gd) // Russian Chemical Bulletin. 2011. Vol. 60. No. 12. pp. 2490-2503.
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Burkovskaya N. P., Orlova E. V., Kiskin M. A., Efimov N. N., Bogomyakov A. S., Fedin M. V., Kolotilov S. V., Minin V. V., Aleksandrov G., Sidorov A. A., Ovcharenko V., Novotortsev V. M., Eremenko I. L. Synthesis, structure, and magnetic properties of heterometallic trinuclear complexes {MII—LnIII—MII} (MII = Ni, Cu; LnIII = La, Pr, Sm, Eu, Gd) // Russian Chemical Bulletin. 2011. Vol. 60. No. 12. pp. 2490-2503.
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TY - JOUR
DO - 10.1007/s11172-011-0384-4
UR - https://doi.org/10.1007/s11172-011-0384-4
TI - Synthesis, structure, and magnetic properties of heterometallic trinuclear complexes {MII—LnIII—MII} (MII = Ni, Cu; LnIII = La, Pr, Sm, Eu, Gd)
T2 - Russian Chemical Bulletin
AU - Burkovskaya, N P
AU - Orlova, E V
AU - Kiskin, M. A.
AU - Efimov, N. N.
AU - Bogomyakov, A S
AU - Fedin, M V
AU - Kolotilov, S V
AU - Minin, V V
AU - Aleksandrov, G.G.
AU - Sidorov, A. A.
AU - Ovcharenko, V.I.
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2011
DA - 2011/12/01
PB - Springer Nature
SP - 2490-2503
IS - 12
VL - 60
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2011_Burkovskaya,
author = {N P Burkovskaya and E V Orlova and M. A. Kiskin and N. N. Efimov and A S Bogomyakov and M V Fedin and S V Kolotilov and V V Minin and G.G. Aleksandrov and A. A. Sidorov and V.I. Ovcharenko and V. M. Novotortsev and I. L. Eremenko},
title = {Synthesis, structure, and magnetic properties of heterometallic trinuclear complexes {MII—LnIII—MII} (MII = Ni, Cu; LnIII = La, Pr, Sm, Eu, Gd)},
journal = {Russian Chemical Bulletin},
year = {2011},
volume = {60},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/s11172-011-0384-4},
number = {12},
pages = {2490--2503},
doi = {10.1007/s11172-011-0384-4}
}
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MLA
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Burkovskaya, N. P., et al. “Synthesis, structure, and magnetic properties of heterometallic trinuclear complexes {MII—LnIII—MII} (MII = Ni, Cu; LnIII = La, Pr, Sm, Eu, Gd).” Russian Chemical Bulletin, vol. 60, no. 12, Dec. 2011, pp. 2490-2503. https://doi.org/10.1007/s11172-011-0384-4.