Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments
M M Levitsky
1
,
A N Bilyachenko
1
,
M S Dronova
2
,
A. I. Dmitriev
3
,
R B Morgunov
3
,
E. S. Shubina
1
,
A D Kirilin
2
Publication type: Journal Article
Publication date: 2012-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Magnetic measurements of individual (manganese,sodium)phenylsilsesquioxane containing eight MnII ions were performed. The magnetic arrangement of manganese ions in this cage-like compound was investigated. The magnetic moment of the cage molecule equals 21 μB (at 300 K), that is a consequence of the mutual antiferromagnetic compensation of four MnII ions, whereas the other four MnII ions have aligned spins. Hence, this metallasiloxane is a promising compound for the chemical design of molecular nanomagnets. At low temperatures, the antiferromagnetic coupling causes a decrease in the effective magnetic moment (to 16 μB at 40 K).
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Levitsky M. M. et al. Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments // Russian Chemical Bulletin. 2012. Vol. 61. No. 1. pp. 200-203.
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Levitsky M. M., Bilyachenko A. N., Dronova M. S., Dmitriev A. I., Morgunov R. B., Shubina E. S., Kirilin A. D. Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments // Russian Chemical Bulletin. 2012. Vol. 61. No. 1. pp. 200-203.
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RIS
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TY - JOUR
DO - 10.1007/s11172-012-0027-4
UR - https://doi.org/10.1007/s11172-012-0027-4
TI - Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments
T2 - Russian Chemical Bulletin
AU - Levitsky, M M
AU - Bilyachenko, A N
AU - Dronova, M S
AU - Dmitriev, A. I.
AU - Morgunov, R B
AU - Shubina, E. S.
AU - Kirilin, A D
PY - 2012
DA - 2012/01/01
PB - Springer Nature
SP - 200-203
IS - 1
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2012_Levitsky,
author = {M M Levitsky and A N Bilyachenko and M S Dronova and A. I. Dmitriev and R B Morgunov and E. S. Shubina and A D Kirilin},
title = {Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s11172-012-0027-4},
number = {1},
pages = {200--203},
doi = {10.1007/s11172-012-0027-4}
}
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MLA
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Levitsky, M. M., et al. “Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments.” Russian Chemical Bulletin, vol. 61, no. 1, Jan. 2012, pp. 200-203. https://doi.org/10.1007/s11172-012-0027-4.
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