Reaction of the PtIII complex, [Pt2(μ-NHCOMe)4Cl2], with 1,10-phenanthroline and solid-state thermolysis of 1,10-phenanthroline-containing platinum blues
T N Fedotova
1
,
Zh V Dobrokhotova
1
,
P S Koroteev
1
,
G. N. Kuznetsova
1
,
G.G. Aleksandrov
1
,
V.K. Ivanov
1
,
E F Zharikova
1
,
Publication type: Journal Article
Publication date: 2012-02-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Platinum blues with the composition Pt(phen)(NHCOMe)2X (phen is 1,10-phenanthroline, X = NO3−, CF3SO3−, or Cl−), were synthesized starting from the complex [Pt2(NHCOMe)4Cl2]. The resulting compounds apparently have a polymeric structure with metal centers in different valence states. The reaction of the complex Pt(phen)(NHCOMe)2NO3 with H2O affords crystalline binuclear acetamidate [PtIII2(phen)2(μ-NHCOMe)2(NHCOMe)2](NO3)2, whose structure was determined by X-ray diffraction. The reaction of the complex Pt(phen)(NHCOMe)2NO3 with HCF3SO3 leads to the decomposition of the starting compound, the reduction of the Pt atoms, and the formation of the complex [PtII2(phen)4](CF3SO3)4. The thermal decomposition of the resulting complexes, as well as the complexes [(phen)Pt-(μ-NHCOMe)2Pt(phen)]2(NO3)4 and [Pt(phen)Cl2], under an inert atmosphere was studied by DSC and TGA. Metallic platinum nanopowders are thermal decomposition products of the complexes under study.
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Fedotova T. N. et al. Reaction of the PtIII complex, [Pt2(μ-NHCOMe)4Cl2], with 1,10-phenanthroline and solid-state thermolysis of 1,10-phenanthroline-containing platinum blues // Russian Chemical Bulletin. 2012. Vol. 61. No. 2. pp. 230-239.
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Fedotova T. N., Dobrokhotova Z. V., Koroteev P. S., Kuznetsova G. N., Aleksandrov G., Ivanov V., Zharikova E. F., Eremenko I. L. Reaction of the PtIII complex, [Pt2(μ-NHCOMe)4Cl2], with 1,10-phenanthroline and solid-state thermolysis of 1,10-phenanthroline-containing platinum blues // Russian Chemical Bulletin. 2012. Vol. 61. No. 2. pp. 230-239.
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TY - JOUR
DO - 10.1007/s11172-012-0033-6
UR - https://doi.org/10.1007/s11172-012-0033-6
TI - Reaction of the PtIII complex, [Pt2(μ-NHCOMe)4Cl2], with 1,10-phenanthroline and solid-state thermolysis of 1,10-phenanthroline-containing platinum blues
T2 - Russian Chemical Bulletin
AU - Fedotova, T N
AU - Dobrokhotova, Zh V
AU - Koroteev, P S
AU - Kuznetsova, G. N.
AU - Aleksandrov, G.G.
AU - Ivanov, V.K.
AU - Zharikova, E F
AU - Eremenko, I. L.
PY - 2012
DA - 2012/02/01
PB - Springer Nature
SP - 230-239
IS - 2
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2012_Fedotova,
author = {T N Fedotova and Zh V Dobrokhotova and P S Koroteev and G. N. Kuznetsova and G.G. Aleksandrov and V.K. Ivanov and E F Zharikova and I. L. Eremenko},
title = {Reaction of the PtIII complex, [Pt2(μ-NHCOMe)4Cl2], with 1,10-phenanthroline and solid-state thermolysis of 1,10-phenanthroline-containing platinum blues},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {feb},
url = {https://doi.org/10.1007/s11172-012-0033-6},
number = {2},
pages = {230--239},
doi = {10.1007/s11172-012-0033-6}
}
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MLA
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Fedotova, T. N., et al. “Reaction of the PtIII complex, [Pt2(μ-NHCOMe)4Cl2], with 1,10-phenanthroline and solid-state thermolysis of 1,10-phenanthroline-containing platinum blues.” Russian Chemical Bulletin, vol. 61, no. 2, Feb. 2012, pp. 230-239. https://doi.org/10.1007/s11172-012-0033-6.