Behavior of octa(benzo-15-crown-5)- and tetrasulfophthalocyanines in the presence of water-soluble C60 compounds
N F Goldshleger
1
,
A B Kornev
1
,
A V Barinov
1
,
P A Troshin
1
,
A. I. Kotelnikov
1
,
V E Baulin
2, 3
,
Publication type: Journal Article
Publication date: 2012-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Octa[(4′-benzo-15-crown-5)oxy]phthalocyanine was shown to dissolve in the presence of water-soluble fullerene compounds C60Cl(NHCH2CH2NH3+)5(−OOCCF3)5 or C60Cl(C6H4CH2CH2COONa)5. The solubilization of phthalocyanine was attributed to the possibility of formation of the hydrogen bonds N-H...O(CH2) and coordination of the sodium cations inside the cavities of the crown ether fragments for the cationic and anionic fullerene derivatives, respectively. Solubilization of the crown-containing phthalocyanine with participation of water-soluble fullerene compounds proceeded with the formation of aggregated forms. A monomeric form of nickel tetrasulfonated phthalocyaninate in the presence of an equimolar amount of C60Cl(NHCH2CH2NH3+)5(−OOCCF3)5 in 50% ethanol is transformed into a dimeric form. The structures of the fullerene-containing compounds and their state in solution facilitate the stacking aggregation of phthalocyanines.
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Goldshleger N. F. et al. Behavior of octa(benzo-15-crown-5)- and tetrasulfophthalocyanines in the presence of water-soluble C60 compounds // Russian Chemical Bulletin. 2012. Vol. 61. No. 6. pp. 1242-1249.
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Goldshleger N. F., Kornev A. B., Barinov A. V., Troshin P. A., Kotelnikov A. I., Baulin V. E., Tsivadze A. Y. Behavior of octa(benzo-15-crown-5)- and tetrasulfophthalocyanines in the presence of water-soluble C60 compounds // Russian Chemical Bulletin. 2012. Vol. 61. No. 6. pp. 1242-1249.
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TY - JOUR
DO - 10.1007/s11172-012-0168-5
UR - http://link.springer.com/10.1007/s11172-012-0168-5
TI - Behavior of octa(benzo-15-crown-5)- and tetrasulfophthalocyanines in the presence of water-soluble C60 compounds
T2 - Russian Chemical Bulletin
AU - Goldshleger, N F
AU - Kornev, A B
AU - Barinov, A V
AU - Troshin, P A
AU - Kotelnikov, A. I.
AU - Baulin, V E
AU - Tsivadze, A. Yu.
PY - 2012
DA - 2012/06/01
PB - Springer Nature
SP - 1242-1249
IS - 6
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2012_Goldshleger,
author = {N F Goldshleger and A B Kornev and A V Barinov and P A Troshin and A. I. Kotelnikov and V E Baulin and A. Yu. Tsivadze},
title = {Behavior of octa(benzo-15-crown-5)- and tetrasulfophthalocyanines in the presence of water-soluble C60 compounds},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {jun},
url = {http://link.springer.com/10.1007/s11172-012-0168-5},
number = {6},
pages = {1242--1249},
doi = {10.1007/s11172-012-0168-5}
}
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MLA
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Goldshleger, N. F., et al. “Behavior of octa(benzo-15-crown-5)- and tetrasulfophthalocyanines in the presence of water-soluble C60 compounds.” Russian Chemical Bulletin, vol. 61, no. 6, Jun. 2012, pp. 1242-1249. http://link.springer.com/10.1007/s11172-012-0168-5.