Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions
N V Zauzolkova
1
,
E. N. Zorina
1
,
A. A. Sidorov
1
,
G.G. Aleksandrov
1
,
A S Lermontov
1
,
V V Minin
1
,
A V Rotov
1
,
E. A. Ugolkova
1
,
N. N. Efimov
1
,
M. A. Kiskin
1
,
V. M. Novotortsev
1
,
Publication type: Journal Article
Publication date: 2012-07-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A reaction of (HPiv)2Cu2(Piv)4 with dimethylmalonic acid dipotassium salt (K2Me2mal) leads to the formation of a cage coordination polymer {(μ-H2O)6K8[(μ-H2O)Cu-(μ3,κ2-Me2mal)(μ6,κ2-Me2mal)]2[Cu2(μ5,κ2-Me2mal)2(μ5,κ2-Me2mal)2]}n (1). It was found that when 1 reacted with CdSO4·8H2O in a mixture of EtOH-H2O (3: 1), the potassium ions in 1 were displaced with cadmium(ii) ions with the formation of a heterometallic 1D-polymer [(κ1-H2O)4CdCu(μ,κ2-Me2mal)2]n (2). Compounds 1 and 2 were characterized by X-ray crystallography and ESR spectroscopy.
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GOST
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Zauzolkova N. V. et al. Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions // Russian Chemical Bulletin. 2012. Vol. 61. No. 7. pp. 1419-1425.
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Zauzolkova N. V., Zorina E. N., Sidorov A. A., Aleksandrov G., Lermontov A. S., Minin V. V., Rotov A. V., Ugolkova E. A., Efimov N. N., Kiskin M. A., Novotortsev V. M., Eremenko I. L. Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions // Russian Chemical Bulletin. 2012. Vol. 61. No. 7. pp. 1419-1425.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11172-012-0183-6
UR - https://doi.org/10.1007/s11172-012-0183-6
TI - Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions
T2 - Russian Chemical Bulletin
AU - Zauzolkova, N V
AU - Zorina, E. N.
AU - Sidorov, A. A.
AU - Aleksandrov, G.G.
AU - Lermontov, A S
AU - Minin, V V
AU - Rotov, A V
AU - Ugolkova, E. A.
AU - Efimov, N. N.
AU - Kiskin, M. A.
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2012
DA - 2012/07/01
PB - Springer Nature
SP - 1419-1425
IS - 7
VL - 61
SN - 1066-5285
SN - 1573-9171
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_Zauzolkova,
author = {N V Zauzolkova and E. N. Zorina and A. A. Sidorov and G.G. Aleksandrov and A S Lermontov and V V Minin and A V Rotov and E. A. Ugolkova and N. N. Efimov and M. A. Kiskin and V. M. Novotortsev and I. L. Eremenko},
title = {Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions},
journal = {Russian Chemical Bulletin},
year = {2012},
volume = {61},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1007/s11172-012-0183-6},
number = {7},
pages = {1419--1425},
doi = {10.1007/s11172-012-0183-6}
}
Cite this
MLA
Copy
Zauzolkova, N. V., et al. “Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions.” Russian Chemical Bulletin, vol. 61, no. 7, Jul. 2012, pp. 1419-1425. https://doi.org/10.1007/s11172-012-0183-6.