Coupling of C-amino aza-substituted heterocycles with an isocyanide ligand in palladium(ii) complex
Publication type: Journal Article
Publication date: 2013-03-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reaction of cis-dichlorobis(2,6-xylylisocyanide)palladium(ii) with 2-aminopyrazine affords a binuclear palladium complex, in which one of the metal atoms is involved in the palladacyclic ligand. In the contrast, the coupling of isocyanide ligands in cis-dichlorobis-(2,6-xylylisocyanide)palladium(ii) with another C-amino aza-substituted heterocycle, viz.,4-acetyl-3-amino-5-methylpyrazole, gives a mononuclear cationic palladium diaminocarbene complex. Both compounds were characterized by elemental analysis, IR spectroscopy, 1H, 13C{1H}, DEPT90/DEPT135, and 1H,13C-HSQC/1H,13C-HMBC NMR spectroscopy, high-resolution electrospray ionization mass spectrometry, and X-ray diffraction.
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Kinzhalov M. A. et al. Coupling of C-amino aza-substituted heterocycles with an isocyanide ligand in palladium(ii) complex // Russian Chemical Bulletin. 2013. Vol. 62. No. 3. pp. 758-766.
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Kinzhalov M. A., Luzyanin K. V., Boyarskiy V. P., Haukka M., Kukushkin V. Y. Coupling of C-amino aza-substituted heterocycles with an isocyanide ligand in palladium(ii) complex // Russian Chemical Bulletin. 2013. Vol. 62. No. 3. pp. 758-766.
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TY - JOUR
DO - 10.1007/s11172-013-0103-4
UR - https://doi.org/10.1007/s11172-013-0103-4
TI - Coupling of C-amino aza-substituted heterocycles with an isocyanide ligand in palladium(ii) complex
T2 - Russian Chemical Bulletin
AU - Kinzhalov, M A
AU - Luzyanin, K V
AU - Boyarskiy, V P
AU - Haukka, M
AU - Kukushkin, V. Yu.
PY - 2013
DA - 2013/03/01
PB - Springer Nature
SP - 758-766
IS - 3
VL - 62
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2013_Kinzhalov,
author = {M A Kinzhalov and K V Luzyanin and V P Boyarskiy and M Haukka and V. Yu. Kukushkin},
title = {Coupling of C-amino aza-substituted heterocycles with an isocyanide ligand in palladium(ii) complex},
journal = {Russian Chemical Bulletin},
year = {2013},
volume = {62},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s11172-013-0103-4},
number = {3},
pages = {758--766},
doi = {10.1007/s11172-013-0103-4}
}
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MLA
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Kinzhalov, M. A., et al. “Coupling of C-amino aza-substituted heterocycles with an isocyanide ligand in palladium(ii) complex.” Russian Chemical Bulletin, vol. 62, no. 3, Mar. 2013, pp. 758-766. https://doi.org/10.1007/s11172-013-0103-4.
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