Complexation of trimeric copper(i) and silver(i) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane
A.A. Titov
1
,
E A Guseva
1
,
A F Smolyakov
1
,
F.M. Dolgushin
1
,
O. A. Filippov
1
,
I E Golub
1
,
A I Krylova
1
,
G M Babakhina
1
,
L M Epstein
1
,
Publication type: Journal Article
Publication date: 2013-08-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A complexation of trimeric copper(i) and silver(i) 3,5-bis(trifluoromethyl)pyrazolates ((ML)3) with BH3NEt3 was studied by IR spectroscopy in hexane and dichloromethane solutions. In hexane, two complexes [(ML)3][BH3NEt3]2 (1) and [(ML)3][BH3NEt3] (2) were formed depending on the ratio of reagents. In dichloromethane, only one complex [(ML)3][BH3NEt3] (2) was found. The thermodynamic parameters (ΔH ○, ΔS ○) of complex 1 in hexane and complex 2 in dichloromethane were obtained. The complex [(AgL)3][BH3NEt3] was isolated in the solid state, its structure was established by X-ray diffraction. The complex is formed due to two bridges B-H-Ag, one BH group is not involved in the complexation. In crystal, molecules 2 form supramolecular dimers due to the intermolecular interactions between metals of two macrocycles.
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GOST
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Titov A. et al. Complexation of trimeric copper(i) and silver(i) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane // Russian Chemical Bulletin. 2013. Vol. 62. No. 8. pp. 1829-1834.
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Titov A., Guseva E. A., Smolyakov A. F., Dolgushin F., Filippov O. A., Golub I. E., Krylova A. I., Babakhina G. M., Epstein L. M., Shubina E. S. Complexation of trimeric copper(i) and silver(i) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane // Russian Chemical Bulletin. 2013. Vol. 62. No. 8. pp. 1829-1834.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s11172-013-0263-2
UR - https://doi.org/10.1007/s11172-013-0263-2
TI - Complexation of trimeric copper(i) and silver(i) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane
T2 - Russian Chemical Bulletin
AU - Titov, A.A.
AU - Guseva, E A
AU - Smolyakov, A F
AU - Dolgushin, F.M.
AU - Filippov, O. A.
AU - Golub, I E
AU - Krylova, A I
AU - Babakhina, G M
AU - Epstein, L M
AU - Shubina, E. S.
PY - 2013
DA - 2013/08/01
PB - Springer Nature
SP - 1829-1834
IS - 8
VL - 62
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
Copy
@article{2013_Titov,
author = {A.A. Titov and E A Guseva and A F Smolyakov and F.M. Dolgushin and O. A. Filippov and I E Golub and A I Krylova and G M Babakhina and L M Epstein and E. S. Shubina},
title = {Complexation of trimeric copper(i) and silver(i) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane},
journal = {Russian Chemical Bulletin},
year = {2013},
volume = {62},
publisher = {Springer Nature},
month = {aug},
url = {https://doi.org/10.1007/s11172-013-0263-2},
number = {8},
pages = {1829--1834},
doi = {10.1007/s11172-013-0263-2}
}
Cite this
MLA
Copy
Titov, A.A., et al. “Complexation of trimeric copper(i) and silver(i) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane.” Russian Chemical Bulletin, vol. 62, no. 8, Aug. 2013, pp. 1829-1834. https://doi.org/10.1007/s11172-013-0263-2.