Structures and magnetic properties of new trinuclear CoII, NiII, and CuII complexes with trimethylacetate and 1,1-cyclohexanediacetate
N. V. Gogoleva
1
,
N. N. Efimov
1
,
E. A. Ugolkova
1
,
A S Bogomyakov
2
,
S V Kolotilov
3
,
M. A. Kiskin
1
,
G.G. Aleksandrov
1
,
V V Minin
1
,
A. A. Sidorov
1
,
V. M. Novotortsev
1
,
3
L. V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
|
Publication type: Journal Article
Publication date: 2014-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reactions of transition metal trimethylacetates [Cu2(Piv)4(HPiv)2], [Ni9(OH)6(Piv)12(HPiv)4], [Co(Piv)2]n (Piv− = −O2CBut) with 1,1-cyclohexanediacetic acid (H2Chda) neutralized by tetrabutylammonium hydroxide in the presence of 2,2-bipyridine (2,2′-bpy) afford linear trinuclear homometallic complexes [(2,2′-bpy)2Cu3(Chda)2(Piv)2]··2EtOH (1) and [(2,2′-bpy)2M3(Chda)2(Piv)2(EtOH)2] (M = NiII (2) or CoII (3)). In molecules of these compounds, anions of both mono- and dicarboxylic acids act as bridges between the transition metal atoms. Compounds 1–3 were characterized by X-ray diffraction, and their magnetic properties were studied. Spin-spin ferromagnetic interactions dominate in complexes 1–3 with CuII (S = 1/2) (1) and CoII (S = 3/2) (3) ions.
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Gogoleva N. V. et al. Structures and magnetic properties of new trinuclear CoII, NiII, and CuII complexes with trimethylacetate and 1,1-cyclohexanediacetate // Russian Chemical Bulletin. 2014. Vol. 63. No. 6. pp. 1301-1307.
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Gogoleva N. V., Zorina-Tikhonova E. N., Efimov N. N., Ugolkova E. A., Bogomyakov A. S., Kolotilov S. V., Kiskin M. A., Aleksandrov G., Minin V. V., Sidorov A. A., Novotortsev V. M., Eremenko I. L. Structures and magnetic properties of new trinuclear CoII, NiII, and CuII complexes with trimethylacetate and 1,1-cyclohexanediacetate // Russian Chemical Bulletin. 2014. Vol. 63. No. 6. pp. 1301-1307.
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TY - JOUR
DO - 10.1007/s11172-014-0594-7
UR - https://doi.org/10.1007/s11172-014-0594-7
TI - Structures and magnetic properties of new trinuclear CoII, NiII, and CuII complexes with trimethylacetate and 1,1-cyclohexanediacetate
T2 - Russian Chemical Bulletin
AU - Gogoleva, N. V.
AU - Zorina-Tikhonova, E. N.
AU - Efimov, N. N.
AU - Ugolkova, E. A.
AU - Bogomyakov, A S
AU - Kolotilov, S V
AU - Kiskin, M. A.
AU - Aleksandrov, G.G.
AU - Minin, V V
AU - Sidorov, A. A.
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2014
DA - 2014/06/01
PB - Springer Nature
SP - 1301-1307
IS - 6
VL - 63
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2014_Gogoleva,
author = {N. V. Gogoleva and E. N. Zorina-Tikhonova and N. N. Efimov and E. A. Ugolkova and A S Bogomyakov and S V Kolotilov and M. A. Kiskin and G.G. Aleksandrov and V V Minin and A. A. Sidorov and V. M. Novotortsev and I. L. Eremenko},
title = {Structures and magnetic properties of new trinuclear CoII, NiII, and CuII complexes with trimethylacetate and 1,1-cyclohexanediacetate},
journal = {Russian Chemical Bulletin},
year = {2014},
volume = {63},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-014-0594-7},
number = {6},
pages = {1301--1307},
doi = {10.1007/s11172-014-0594-7}
}
Cite this
MLA
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Gogoleva, N. V., et al. “Structures and magnetic properties of new trinuclear CoII, NiII, and CuII complexes with trimethylacetate and 1,1-cyclohexanediacetate.” Russian Chemical Bulletin, vol. 63, no. 6, Jun. 2014, pp. 1301-1307. https://doi.org/10.1007/s11172-014-0594-7.